引用本文:
Xin Ying Zhang, Ying Ying Qu, Yang Yang Wang, Xue Sen Fan. Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI[J]. Chinese Chemical Letters,
2011, 22(3): 268-271.
doi:
10.1016/j.cclet.2010.09.032
Citation: Xin Ying Zhang, Ying Ying Qu, Yang Yang Wang, Xue Sen Fan. Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI[J]. Chinese Chemical Letters, 2011, 22(3): 268-271. doi: 10.1016/j.cclet.2010.09.032
Citation: Xin Ying Zhang, Ying Ying Qu, Yang Yang Wang, Xue Sen Fan. Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI[J]. Chinese Chemical Letters, 2011, 22(3): 268-271. doi: 10.1016/j.cclet.2010.09.032
Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI
摘要:
A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones. The advantages of this procedure include short reaction time, less adverse impact on the environment and reasonably high efficiency.
English
Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI
Abstract:
A CrO3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones. The advantages of this procedure include short reaction time, less adverse impact on the environment and reasonably high efficiency.
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Key words:
- Allenic ketones
- / Oxidation
- / Microwave irradiation
- / Chromium(VI)oxide
- / tert-Butyl hydroperoxide
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