引用本文:
Ling Hong WENG, Xue Tai CHEN, Yong Han HU, Bei Sheng KANG. TRIPLY BRIDGED BINUCLEAR COMPLEX OF OXOMOLYBDENUM(Ⅴ)WITH MERCAPTOPHENOLATE LIGANDS[J]. Chinese Chemical Letters,
1991, 2(4): 315-316.
Citation: Ling Hong WENG, Xue Tai CHEN, Yong Han HU, Bei Sheng KANG. TRIPLY BRIDGED BINUCLEAR COMPLEX OF OXOMOLYBDENUM(Ⅴ)WITH MERCAPTOPHENOLATE LIGANDS[J]. Chinese Chemical Letters, 1991, 2(4): 315-316.
Citation: Ling Hong WENG, Xue Tai CHEN, Yong Han HU, Bei Sheng KANG. TRIPLY BRIDGED BINUCLEAR COMPLEX OF OXOMOLYBDENUM(Ⅴ)WITH MERCAPTOPHENOLATE LIGANDS[J]. Chinese Chemical Letters, 1991, 2(4): 315-316.
TRIPLY BRIDGED BINUCLEAR COMPLEX OF OXOMOLYBDENUM(Ⅴ)WITH MERCAPTOPHENOLATE LIGANDS
摘要:
Reaction of(n-Bu4N)xNa4-x[a-Mo8O26](x=1-4)and mpH2(mpH2=o-mercaptophenol) leads to the formation of compound(n-Bu4N)[Mo2O3(mp)3Na(EtOH)2(MeOH)],It crystallizes in the space group P21/n with four molecules per unit cell.The cell dimension is a=12.776(3),b=14.154(5),c=26.281(7) Å,β=95.50(2)°,V=4730.5Å3,dc=1.407g/cm3.Full-matrix refinement of 496 parameters on 3348 reflection data gave final R(Rw)value of 0.072(0.072).The two oxomolybdenum-mercaptophenolate,units are triply bridged by an inorganic oxygen atom and a doubly bridging mp2-ligand.
English
TRIPLY BRIDGED BINUCLEAR COMPLEX OF OXOMOLYBDENUM(Ⅴ)WITH MERCAPTOPHENOLATE LIGANDS
Abstract:
Reaction of(n-Bu4N)xNa4-x[a-Mo8O26](x=1-4)and mpH2(mpH2=o-mercaptophenol) leads to the formation of compound(n-Bu4N)[Mo2O3(mp)3Na(EtOH)2(MeOH)],It crystallizes in the space group P21/n with four molecules per unit cell.The cell dimension is a=12.776(3),b=14.154(5),c=26.281(7) Å,β=95.50(2)°,V=4730.5Å3,dc=1.407g/cm3.Full-matrix refinement of 496 parameters on 3348 reflection data gave final R(Rw)value of 0.072(0.072).The two oxomolybdenum-mercaptophenolate,units are triply bridged by an inorganic oxygen atom and a doubly bridging mp2-ligand.
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