引用本文:
Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters,
2006, 17(6): 841-844.
Citation: Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters, 2006, 17(6): 841-844.
Citation: Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters, 2006, 17(6): 841-844.
Enhanced Acid/Base Catalysis in High Temperature Liquid Water
摘要:
Two novel and environmentally benign solvent systems, organic acids-enriched high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
English
Enhanced Acid/Base Catalysis in High Temperature Liquid Water
Abstract:
Two novel and environmentally benign solvent systems, organic acids-enriched high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
-
Key words:
- High temperature liquid water
- / acid/base-catalysis
- / organic reactions
扫一扫看文章
计量
- PDF下载量: 1
- 文章访问数: 1140
- HTML全文浏览量: 17
下载:
