引用本文:
Feng SHI, Hong Yang LI, Xiao Jun PENG, Rong ZHANG, Xiao Qiang CHEN, Jiang Li FAN, Jing Nan CUI, Björn Åkermark, Li Cheng SUN. Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups[J]. Chinese Chemical Letters,
2005, 16(1): 89-92.
Citation: Feng SHI, Hong Yang LI, Xiao Jun PENG, Rong ZHANG, Xiao Qiang CHEN, Jiang Li FAN, Jing Nan CUI, Björn Åkermark, Li Cheng SUN. Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups[J]. Chinese Chemical Letters, 2005, 16(1): 89-92.
Citation: Feng SHI, Hong Yang LI, Xiao Jun PENG, Rong ZHANG, Xiao Qiang CHEN, Jiang Li FAN, Jing Nan CUI, Björn Åkermark, Li Cheng SUN. Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups[J]. Chinese Chemical Letters, 2005, 16(1): 89-92.
Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups
摘要:
Two novel high valent complexes [M2(Ⅲ, Ⅲ)L(μ-OAc)2]·PF6(M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl) (pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(Ⅱ, Ⅱ) (bpmp) (μ-OAc2)·CLO4 (10).These improvements decreascd the difference beteween the mew mode and (Mn)4 cluster (OEC in nature).
English
Synthesis and Characterization of Two Novel High Valent Dinuclear Complexes with a Triphenolate Ligand Bearing Functional Groups
Abstract:
Two novel high valent complexes [M2(Ⅲ, Ⅲ)L(μ-OAc)2]·PF6(M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl) (pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(Ⅱ, Ⅱ) (bpmp) (μ-OAc2)·CLO4 (10).These improvements decreascd the difference beteween the mew mode and (Mn)4 cluster (OEC in nature).
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Key words:
- Dinuclear complex
- / OEC
- / artificial photosynthesis.
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