引用本文:
Jing Yang, Shou Li Bai, Rui Xian Luo, Ai Fan Chen, Yuan Lin, Jing Bo Zhang. Electrodeposition of SnO2 nanocrystalline thin film using butyl-rhodamine B as a structure-directing agent[J]. Chinese Chemical Letters,
2010, 21(12): 1505-1508.
doi:
10.1016/j.cclet.2010.07.004
Citation: Jing Yang, Shou Li Bai, Rui Xian Luo, Ai Fan Chen, Yuan Lin, Jing Bo Zhang. Electrodeposition of SnO2 nanocrystalline thin film using butyl-rhodamine B as a structure-directing agent[J]. Chinese Chemical Letters, 2010, 21(12): 1505-1508. doi: 10.1016/j.cclet.2010.07.004
Citation: Jing Yang, Shou Li Bai, Rui Xian Luo, Ai Fan Chen, Yuan Lin, Jing Bo Zhang. Electrodeposition of SnO2 nanocrystalline thin film using butyl-rhodamine B as a structure-directing agent[J]. Chinese Chemical Letters, 2010, 21(12): 1505-1508. doi: 10.1016/j.cclet.2010.07.004
Electrodeposition of SnO2 nanocrystalline thin film using butyl-rhodamine B as a structure-directing agent
摘要:
Porous SnO2 nanocrystalline thin films were successfully electrodeposited from an oxygen-saturated acid aqueous solution of SnCl2 containing different concentrations of butyl-rhodamine B (BRhB) at 70℃. BRhB with substitute of amidocyanogen can be dissolved in the acid deposition solution, where HCl was added to suppress hydrolysis of SnCl2. So it was used as a structure-directing agent to promote the crystal growth of SnO2. The formed porous morphology and tetragonal rutile crystalline structure of the electrodeposited thin films were controlled by the addition of BRhB with different amounts.
English
Electrodeposition of SnO2 nanocrystalline thin film using butyl-rhodamine B as a structure-directing agent
Abstract:
Porous SnO2 nanocrystalline thin films were successfully electrodeposited from an oxygen-saturated acid aqueous solution of SnCl2 containing different concentrations of butyl-rhodamine B (BRhB) at 70℃. BRhB with substitute of amidocyanogen can be dissolved in the acid deposition solution, where HCl was added to suppress hydrolysis of SnCl2. So it was used as a structure-directing agent to promote the crystal growth of SnO2. The formed porous morphology and tetragonal rutile crystalline structure of the electrodeposited thin films were controlled by the addition of BRhB with different amounts.
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