引用本文:
Zheng Bai CAO, Han Zhang WANG, Zhen Rong LU, Li Min ZHU, Jian Sheng GU, Song Shan GUO, Kai Bei YU. CRYSTAL STRUCTURE OF DI-NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2[J]. Chinese Chemical Letters,
1992, 3(3): 211-212.
Citation: Zheng Bai CAO, Han Zhang WANG, Zhen Rong LU, Li Min ZHU, Jian Sheng GU, Song Shan GUO, Kai Bei YU. CRYSTAL STRUCTURE OF DI-NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2[J]. Chinese Chemical Letters, 1992, 3(3): 211-212.
Citation: Zheng Bai CAO, Han Zhang WANG, Zhen Rong LU, Li Min ZHU, Jian Sheng GU, Song Shan GUO, Kai Bei YU. CRYSTAL STRUCTURE OF DI-NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2[J]. Chinese Chemical Letters, 1992, 3(3): 211-212.
CRYSTAL STRUCTURE OF DI-NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2
摘要:
The crystal structure of Di-nitratobis (ethylcaprolactam)uranyl (Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2 was established by a single-crystal X-ray diffraction study.It is triclinie, space group P1, with a=7.171 (2), b=8.655 (3), c=10.182 (5)Å, α=78.27 (3), β=70.63 (3), γ=81.76 (3)°, V=581.7 (4)Å3, Z=l, Dc=1.94 g.cm-3.Final R value is 0.0218.The result reveals that uranyl ion is coordinated to six oxygen atoms, two of them are from two carbonyl groups of ethylcaprolactam and the other four are from two nitrate groups.
English
CRYSTAL STRUCTURE OF DI-NITRATOBIS(ETHYLCAPROLACTAM)URANYL(Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2
Abstract:
The crystal structure of Di-nitratobis (ethylcaprolactam)uranyl (Ⅱ) UO2 [CH2 (CH2)4 CONC2H5]2 (NO3)2 was established by a single-crystal X-ray diffraction study.It is triclinie, space group P1, with a=7.171 (2), b=8.655 (3), c=10.182 (5)Å, α=78.27 (3), β=70.63 (3), γ=81.76 (3)°, V=581.7 (4)Å3, Z=l, Dc=1.94 g.cm-3.Final R value is 0.0218.The result reveals that uranyl ion is coordinated to six oxygen atoms, two of them are from two carbonyl groups of ethylcaprolactam and the other four are from two nitrate groups.
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