引用本文:
Jia Sheng GUO, Xiao Tian LIANG. STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE[J]. Chinese Chemical Letters,
1991, 2(3): 189-190.
Citation: Jia Sheng GUO, Xiao Tian LIANG. STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE[J]. Chinese Chemical Letters, 1991, 2(3): 189-190.
Citation: Jia Sheng GUO, Xiao Tian LIANG. STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE[J]. Chinese Chemical Letters, 1991, 2(3): 189-190.
STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE
摘要:
The configuration of the hydroxy acid 2, a product from base-catalyzed autoxidation of 3α, 5-cyclo-5α-cholestane-6-one, was established on the basis of NMR techniques and the mechanism of the formation of 2 was discussed.
English
STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE
Abstract:
The configuration of the hydroxy acid 2, a product from base-catalyzed autoxidation of 3α, 5-cyclo-5α-cholestane-6-one, was established on the basis of NMR techniques and the mechanism of the formation of 2 was discussed.
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