引用本文:
Chang Wen HU, Qing Lin HE, Yong Hua ZHANG, Tian Di TANG, En Bo WANG. STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW11O39Z(H2O)n-[J]. Chinese Chemical Letters,
1995, 6(7): 609-612.
Citation: Chang Wen HU, Qing Lin HE, Yong Hua ZHANG, Tian Di TANG, En Bo WANG. STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW11O39Z(H2O)n-[J]. Chinese Chemical Letters, 1995, 6(7): 609-612.
Citation: Chang Wen HU, Qing Lin HE, Yong Hua ZHANG, Tian Di TANG, En Bo WANG. STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW11O39Z(H2O)n-[J]. Chinese Chemical Letters, 1995, 6(7): 609-612.
STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW11O39Z(H2O)n-
摘要:
ZnAl hydrotalcites have been intercalated by THPOMs[BW11O39Z(H2O)n-(Z=Ni2+, Cu2+ and Al3+)] via both hydrothermal reaction and ion exchange reaction.The spectra of powder X-ray diffraction and IR show that the synthesized complexes pillared by THPOMs are layered compounds with gallery heights of 9.7~9.9Å, The anions entering the layer retain their Keggin structure.
English
STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW11O39Z(H2O)n-
Abstract:
ZnAl hydrotalcites have been intercalated by THPOMs[BW11O39Z(H2O)n-(Z=Ni2+, Cu2+ and Al3+)] via both hydrothermal reaction and ion exchange reaction.The spectra of powder X-ray diffraction and IR show that the synthesized complexes pillared by THPOMs are layered compounds with gallery heights of 9.7~9.9Å, The anions entering the layer retain their Keggin structure.
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