引用本文:
张建辉, 陈小娟, 余小岚, 张伟庆. 微孔物质BET测试数据的筛选、处理和检验[J]. 大学化学,
2019, 34(3): 53-59.
doi:
10.3866/PKU.DXHX201807015
Citation: ZHANG Jianhui, CHEN Xiaojuan, YU Xiaolan, ZHANG Weiqing. Screening, Processing and Checking of BET Test Data[J]. University Chemistry, 2019, 34(3): 53-59. doi: 10.3866/PKU.DXHX201807015
Citation: ZHANG Jianhui, CHEN Xiaojuan, YU Xiaolan, ZHANG Weiqing. Screening, Processing and Checking of BET Test Data[J]. University Chemistry, 2019, 34(3): 53-59. doi: 10.3866/PKU.DXHX201807015
微孔物质BET测试数据的筛选、处理和检验
摘要:
经典的BET测试适用于介孔和无孔物质，测试的相对压力范围是p/p0=0.05–0.3。现在人们对含有微孔的物质也用BET表征，可能的测试相对压力范围是p/p0=0.005–0.3。所得数据比较多，需要筛选才能找出符合BET模型的数据。有的仪器公司最新版软件有辅助筛选功能，使用起来非常方便。这类软件是基于Rouquerol变换方法编写的。我们试着摸索了这个方法的数学推导过程，然后根据文献和多人积累的测试经验归纳总结出了BET数据处理的5个步骤，整个处理过程在Origin软件上即可实现，适用于所有容量法BET仪器的数据筛选、处理和检验。
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关键词:
- BET测试
- / Rouquerol变换
- / 数据筛选
- / Origin软件
English
Screening, Processing and Checking of BET Test Data
Abstract:
The classic BET test is applicable to mesoporous and nonporous materials, and the relative pressure (p/p0) range is 0.05-0.3. Currently, BET is also used to characterize the substances containing microspores. The relative pressure range is 0.005-0.3. The large amount data need to be screened to find out the data that conform to the BET model. Some of the latest software provided by the instrumental company have very convenient auxiliary screening function, which is written based on Rouquerol transform method. We tried to find out the mathematical deduction process of this method. Then, according to the literature and the testing experience by many individuals, we summed up the 5 steps of BET data processing. The entire process can be realized on the Origin software. It is suitable for the data screening, processing and checking of all volumetric BET methods.
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Key words:
- BET test
- / Rouquerol transform
- / Data screening
- / Origin software
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[1] 杨正红, 高原. 现代科学仪器, 2010, No. 1, 97.
-
[2] 梁薇. 工业催化, 2006, 14 (11), 66.
-
[3] 刘丽萍. 中国粉体技术, 2014, 20 (4), 68.
-
[4] Rouquerol, J.; Llewellyn, P.; Rouquerol, F. Stud. Surf. Sci. Catal. 2007, 106, 49.
-
[5] 数据点的自动选择和BET表面积的优化.[2018-05-24]. http://www.micromeritics.com.cn/Upload/2013/07/23/1748476109.pdf.
-
[6] 魏芸, 李忠全, 汪俊琴, 张宪铭. 气体吸附BET法测定固态物质比表面积:中华人民共和国国家标准, GB/T19587-2004. 2004-09-29
-
[7] 中国科学院数学研究所数理统计组. 回归分析方法. 北京:科学出版社, 1975:5−12, 50.
-
[8] 近藤精一, 石川达雄, 安部郁夫. 吸附科学(原著第二版). 李国希, 译. 北京:化学工业出版社, 2006:40−47, 55.
-
[9] 赵国锋, 柳召永, 王艳飞, 代晓东, 刘欣梅, 阎子峰. 分子催化, 2007, 21 (增刊), 681.
-
[10] 童祜嵩. 颗粒粒度与比表面测量原理. 上海:上海科学技术文献出版社, 1989:286−289.
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