Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials

Hao Chen Xing Xu He Gang Yan Xian Rong Cai Ying Li Qing Jiang Ming Gui Xie

引用本文: Hao Chen,  Xing Xu,  He Gang Yan,  Xian Rong Cai,  Ying Li,  Qing Jiang,  Ming Gui Xie. Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials[J]. Chinese Chemical Letters, 2007, 18(12): 1496-1500. doi: 10.1016/j.cclet.2007.10.005 shu
Citation:  Hao Chen,  Xing Xu,  He Gang Yan,  Xian Rong Cai,  Ying Li,  Qing Jiang,  Ming Gui Xie. Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials[J]. Chinese Chemical Letters, 2007, 18(12): 1496-1500. doi: 10.1016/j.cclet.2007.10.005 shu

Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials

  • 基金项目:

    This work was supported by the key Foundation of Education Ministry of China (No.105142).

摘要: A series of novel fluorene-carbazole-based copolymers with pyrazoline and benzothiazole units were synthesized successfully through Suzuki coupling reactions. The molecular structures and thermal properties of these polymers were characterized by FT-IR, 1H NMR, DSC and TGA. GPC results indicated that the weight-average molecular weight (Mw) and polydispersity of these polymers were in range (12, 000-14, 000) and (1.8-2.0), respectively. The two resulting polymers have high photoluminescence quantum efficiency implying that they may be promising candidates for polymer light-emitting diodes (PLEDs).

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  • 收稿日期:  2007-06-26
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