An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride

Zhi Bin XU Zong Ru GUO

引用本文: Zhi Bin XU,  Zong Ru GUO. An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride[J]. Chinese Chemical Letters, 2003, 14(2): 133-134. shu
Citation:  Zhi Bin XU,  Zong Ru GUO. An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride[J]. Chinese Chemical Letters, 2003, 14(2): 133-134. shu

An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride

摘要: N-(2,4-Dinitrophenyl)-4-amino-n-butyl aldehyde 3 was obtained with high yield of 80% when N-(2,4-dinitrophenyl)-L-proline 1 reacted with SOCl2 at room temperature.However, the anticipated product N-(2,4-dinitrophenyl)-tetrahydropyrrolyl-2-(4-methylthiophenyl) ketone 2 did not be produced.The mechanism was discussed in this article.

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  • 收稿日期:  2002-04-15
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