引用本文:
连英惠, 李丽芳, 赵凡, 赵文洁. 羧甲基纤维素钠/蒙脱土悬浮体系的流变性能及其影响因素[J]. 应用化学,
2013, 30(10): 1208-1214.
doi:
10.3724/SP.J.1095.2013.20553
Citation: LIAN Yinghui, LI Lifang, ZHAO Fan, ZHAO Wenjie. Rheologic Property and Influencing Factors of Sodium Carboxymethyl Cellulose/Montmorillonite Suspension[J]. Chinese Journal of Applied Chemistry, 2013, 30(10): 1208-1214. doi: 10.3724/SP.J.1095.2013.20553
Citation: LIAN Yinghui, LI Lifang, ZHAO Fan, ZHAO Wenjie. Rheologic Property and Influencing Factors of Sodium Carboxymethyl Cellulose/Montmorillonite Suspension[J]. Chinese Journal of Applied Chemistry, 2013, 30(10): 1208-1214. doi: 10.3724/SP.J.1095.2013.20553
羧甲基纤维素钠/蒙脱土悬浮体系的流变性能及其影响因素
摘要:
考察了蒙脱土(MT)质量分数(w)、羧甲基纤维素钠(CMC)/MT质量比(R)、电解质(NaCl、MgCl2和AlCl3)、pH值和温度对MT或CMC/MT悬浮体系流变性能和触变性的影响。结果表明,随w增加,纯MT悬浮体系的流体类型由近牛顿流体向塑型流体变化,触变类型则由无触变、正触变向复合触变性转变;而CMC/MT悬浮体系仍保持MT体系的正触变塑型流体特征,但屈服值τ0和稠度指数K增加,滞后环面积S和电动电势|ζ|先增加后减小,表现出同步变化。电解质和实验温度均不改变CMC/MT悬浮体系的正触变性塑型流体特征,但电解质使τ0和K增加,而温度增加使τ0和K减小。随介质pH值的增加,CMC/MT体系由负触变性变为正触变性,|ζ|增大,S先增加后减小,且在pH=8.46时达到最大。
English
Rheologic Property and Influencing Factors of Sodium Carboxymethyl Cellulose/Montmorillonite Suspension
Abstract:
In order to unveil the rheological properties of suspensions of montmorillonite (MT) and its mixture with sodium carboxymethyl cellulose (CMC)/MT,the effects of the mass fraction w of MT,mass ratio R of CMC to MT,electrolyte,pH and experimental temperature on such properties have been systematically studied. When w(MT) was increased from 1.0% to 3.0%,pure MT suspension changed from Newtonianlike fluid to plastic one,and the thixotropic type changed from non-thixotropy to positive thixotropy and then a complex one. For CMC/MT plastic suspension,the increase of R(fixing w(MT)=2.0% in all the systems)would cause the yield value(τ0) and consistency coefficient (K) to increase as well. The hysteresis loop area(S) increased initially and then decreased,which was accompanied with a synchronous variation of the absolute zeta potential value(|ζ|). The plastic and thixotropic characters of CMC/MT suspension could not be altered by either the electrolytes or experimental temperature investigated. But the yield value τ0 and consistency coefficient K would increase with the increase of electrolyte (NaCl,MgCl2 and AlCl3) concentrations or the decrease of experimental temperature. With the increase of pH value of CMC/MT suspension,its thixotropic type was transformed from negative into positive and the|ζ|incresesd,meanwhile the S firstly increased and then decreased and its maximum value was reached at pH=8.46.
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Key words:
- montmorillonite
- / sodium carboxymethyl cellulose
- / rheology
- / thixotropy
- / hysteresis loop
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