引用本文:
Lai Jin TIAN, Zhi Cai SHANG, Qing Sen YU, Wen Na ZHAO, Bing ZHANG. Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide[J]. Chinese Chemical Letters,
2002, 13(12): 1168-1169.
Citation: Lai Jin TIAN, Zhi Cai SHANG, Qing Sen YU, Wen Na ZHAO, Bing ZHANG. Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide[J]. Chinese Chemical Letters, 2002, 13(12): 1168-1169.
Citation: Lai Jin TIAN, Zhi Cai SHANG, Qing Sen YU, Wen Na ZHAO, Bing ZHANG. Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide[J]. Chinese Chemical Letters, 2002, 13(12): 1168-1169.
Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide
摘要:
The title complex, Cl3SnCH2CH(CH3)CO2CH3·L (1), was synthesized by the reaction of methyl 2-methyl-3-trichlorostannylpropionate with benzylmethylsulfoxide (L) in solid state at room temperature and readily underwent transesterification into the corresponding analogues Cl3SnCH2CH(CH3)CO2R·L when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism of transesterification was suggested.
English
Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide
Abstract:
The title complex, Cl3SnCH2CH(CH3)CO2CH3·L (1), was synthesized by the reaction of methyl 2-methyl-3-trichlorostannylpropionate with benzylmethylsulfoxide (L) in solid state at room temperature and readily underwent transesterification into the corresponding analogues Cl3SnCH2CH(CH3)CO2R·L when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism of transesterification was suggested.
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