引用本文:
Rui Fang SONG, Fei LI, Guang Min LIU, You Gang MAO, Fei DU. THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]2-EGTA AND [Mo(VI)]2-EGTA BY 1HNMR[J]. Chinese Chemical Letters,
1996, 7(6): 567-568.
Citation: Rui Fang SONG, Fei LI, Guang Min LIU, You Gang MAO, Fei DU. THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]2-EGTA AND [Mo(VI)]2-EGTA BY 1HNMR[J]. Chinese Chemical Letters, 1996, 7(6): 567-568.
Citation: Rui Fang SONG, Fei LI, Guang Min LIU, You Gang MAO, Fei DU. THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]2-EGTA AND [Mo(VI)]2-EGTA BY 1HNMR[J]. Chinese Chemical Letters, 1996, 7(6): 567-568.
THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]2-EGTA AND [Mo(VI)]2-EGTA BY 1HNMR
摘要:
The 1H and 13C NMR spectra of the dinuclear complexes of molybdenum (Ⅵ) with ethylenediaminetetraacetic acid ([Mo(VI)]2-EDTA) and 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetra-decanedioic acid([Mo(VI)]2-EGTA) at various temperatures were measured.The solution structure of the two dinuclear complexes was determined and the possible exchange process of the isomers is suggested.
English
THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES [Mo(VI)]2-EGTA AND [Mo(VI)]2-EGTA BY 1HNMR
Abstract:
The 1H and 13C NMR spectra of the dinuclear complexes of molybdenum (Ⅵ) with ethylenediaminetetraacetic acid ([Mo(VI)]2-EDTA) and 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetra-decanedioic acid([Mo(VI)]2-EGTA) at various temperatures were measured.The solution structure of the two dinuclear complexes was determined and the possible exchange process of the isomers is suggested.
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