Correlation between Polymerization of Cyclic Butylene Terephthalate (CBT) and Crystallization of Polymerized CBT

Jian-qiang Zhang Zhi-fang Li Zheng Zhang Hui-xia Feng Zong-bao Wang Ya Li Peng Chen Qun Gu

Citation:  Jian-qiang Zhang, Zhi-fang Li, Zheng Zhang, Hui-xia Feng, Zong-bao Wang, Ya Li, Peng Chen, Qun Gu. Correlation between Polymerization of Cyclic Butylene Terephthalate (CBT) and Crystallization of Polymerized CBT[J]. Chinese Journal of Polymer Science, 2015, 33(8): 1104-1113. doi: 10.1007/s10118-015-1662-7 shu

Correlation between Polymerization of Cyclic Butylene Terephthalate (CBT) and Crystallization of Polymerized CBT

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 21364004), Gansu Province University Fundamental Research Funds and Doctor Research Fund of Lanzhou University of Technology, China.

摘要: The correlation between ring-opening polymerization (ROP) of cyclic butylene terephthalate (CBT) and crystallization of polymerized CBT (pCBT) strongly affected the final properties of pCBT and its composites. The major objective of this contribution is to pinpoint the threshold temperature between them and the interrelation is successfully disclosed. That is, crystallization during polymerization occurs below 204 ℃ and the crystallization properties of pCBT are determined by this isothermal ROP stage; polymerization and crystallization are gradually separated with the increase of temperature of ROP (TP) from 204 ℃, and the crystallization properties of pCBT are dominated by cooling stage; only polymerization is performed above 212 ℃. Moreover, quantitative analysis suggests that uniform crystal size distributions and thicker lamellar crystals derive from the stage of crystallization during polymerization. On the contrary, the crystal size distributions become wider above 204 ℃ of TP and lead to obvious double melting peaks during heating scan. These efforts provide a very useful guide for the related investigation and application of CBT.

English

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    1. [1]

      Brunelle, D.J., Bradt, J.E., Serth-Guzzo, J., Takekoshi, T., Evans, T.L., Pearce, E.J. and Wilson, P.R., Macromolecules, 1998, 31: 4782

    2. [2]

      Miller, S., Ph.D Dissertation, University of Massachusetts Amherst, 1998

    3. [3]

      Tripathy, A.R., Chen, W., Kukureka, S.N. and MacKnight, W.J., Polymer, 2003, 44: 1835

    4. [4]

      Tripathy, A.R., MacKnight, W.J. and Kukureka, S.N., Macromolecules, 2004, 37: 6793

    5. [5]

      Tripathy, A.R., Elmoumni, A., Winter, H.H. and MacKnight, W.J., Macromolecules, 2005, 38: 709

    6. [6]

      McLauchlin, A., Bao, X. and Zhao, F., Appl. Clay Sci., 2011, 53: 749

    7. [7]

      Jiang, Z., Siengchin, S., Zhou, L.M., Steeg, M., Karger-Kocsis, J. and Man, H.C., Compos. Part A-Appl. S., 2009, 40: 273

    8. [8]

      Wu, F.J. and Yang, G.S., J. Appl. Polym. Sci., 2010, 118: 2929

    9. [9]

      Wan, C.Y., Zhao, F., Bao, X.J., Kandasubramanian, B. and Duggan, M., J. Phys. Chem. B., 2008, 112: 11915

    10. [10]

      Fabbri, P., Bassoli, E., Bon, S.B. and Valentini, L., Polymer, 2012, 53: 897

    11. [11]

      Xu, D. and Karger-Kocsis, J., Tribol. Int., 2010, 43: 289

    12. [12]

      Samsudin, S.A., Kukureka, S.N. and Jenkins, M.J., J. Appl. Polym. Sci., 2012, 126: E290

    13. [13]

      Parton, H., Baets, J., Lipnik, P., Goderis, B., Devaux, J. and Verpoest, I., Polymer, 2005, 46: 871

    14. [14]

      Parton, H., Ph. D Dissertation, Katholieke Universiteit Leuven, Belgium, 2006

    15. [15]

      Baets, J., Dutoit, M., Devaux, J. and Verpoest, I., Compos. Part A-Appl. S., 2008, 39: 13

    16. [16]

      Baets, J., Godara, A., Devaux, J. and Verpoest, I., Compos. Part A-Appl. S., 2008, 39: 1756

    17. [17]

      Baets, J., Godara, A., Devaux, J. and Verpoest, I., Polym. Degrad. Stab., 2010, 95: 346

    18. [18]

      Verrey, J., Wakeman, M.D., Michaud, V. and Mnson, J.A., Compos. Part A-Appl. S., 2006, 37: 9

    19. [19]

      Radusch, H.J., Handbook of thermoplastic polymers: Homopolymers, copolymers, blends, and composites, Wiely-Vch Verlag GmbH, Weinheim: 2002

    20. [20]

      Chang, E.P. and Slagowski, E.L., J. Appl. Polym. Sci., 1978, 22: 769

    21. [21]

      Roche, E.J., Stein, R.S. and Thomas, E.L., J. Polym. Sci., Polym. Phys., 1980, 18: 1145

    22. [22]

      Stein, R.S. and Misra, A., J. Polym. Sci., Polym. Phys., 1980, 18: 327

    23. [23]

      Misra, A. and Garg, S.N., J. Polym. Sci., Polym. Lett., 1982, 20: 121

    24. [24]

      Ludwig, H.J. and Eyerer, P., Polym. Eng. Sci., 1988, 28: 143

    25. [25]

      Di Lorenzo, M.L. and Righetti, M.C., Polym. Eng. Sci., 2003, 43: 1889

    26. [26]

      Yoshioka, T., Fujimura, T., Manabe, N., Yokota, Y. and Tsuji, M., Polymer, 2007, 48: 5780

    27. [27]

      Wu, C.M. and Jiang, C.W., J. Polym. Sci., Part B: Polym. Phys., 2010, 48: 1127

    28. [28]

      Moginger, B., Lutz, C., Polsak, A. and Fritz, U., Kunststoffe German Plastics, 1991, 81: 251

    29. [29]

      Hakm, C., Stevenson, I., Maazouz, A., Cassagnau, P., Boiteux, G. and Seytre, G., J. Non-Cryst. Solids, 2007, 353: 4362

    30. [30]

      Archer, E., McIlhagger, A.T., McIlhagger, R., Quinn, J.P., Mallon, P. and Bradaigh, C.O., Polym. Polym. Compos., 2008, 16: 365

    31. [31]

      Lehmann, B. and Karger-Kocsis, J., J. Therm. Anal. Calorim., 2009, 95: 221

    32. [32]

      Lanciano, G., Greco, A., Maffezzoli, A. and Mascia, L., Thermochim. Acta, 2009, 493: 61

    33. [33]

      Bryant, J.J.L. and Semlyen, J.A., Polymer, 1997, 38: 4531

    34. [34]

      Chen, H., Yu, W. and Zhou, C., Polym. Eng. Sci., 2012, 52: 91

    35. [35]

      Zhang, J.Q., Wang, Z.B., Wang, B.J., Gou, Q.T., Zhang, J.W., Zhou, J., Li, Y., Chen, P. and Gu, Q., Polym. Chem., 2013, 4: 1648

    36. [36]

      Wunderlich, B., Macromolecular physics, crystal melting. Academic Press, New York, 1980

    37. [37]

      Yeh, J.T. and Runt, J., J. Polym. Sci., Part B: Polym. Phys., 1989, 27: 1543

    38. [38]

      Cheng, S.Z.D., Pan, R. and Wunderlich, B., Makromol. Chem., 1988, 189: 2443

    39. [39]

      Cheng, Y.Y., Brillhart, M.V. and Cebe, P., Thermochim. Acta, 1997, 305: 369

    40. [40]

      Hsiao, B.S. Wang, Z.G., Yeh, F.J., Gao, Y. and Sheth, K.C., Polymer, 1999, 40: 3515

    41. [41]

      Righetti, M.C., Thermochim. Acta, 1999, 330: 131

    42. [42]

      Supaphol, P., Dangseeyun, N., Srimoaon, P. and Nithitanakul, M., Thermochim. Acta, 2003, 406: 207

    43. [43]

      Dangseeyun, N., Srimoaon, P., Supaphol, P. and Nithitanakul, M., Thermochim. Acta, 2004, 409: 63

    44. [44]

      Huang, J.W., Wen, Y.L., Kang, C.C., Yeh, M.Y. and Wen, S.B., Thermochim. Acta, 2007, 465: 48

    45. [45]

      Nichols, M.E. and Robertson, R.E., J. Polym. Sci., Part B: Polym. Phys., 1992, 30: 755

    46. [46]

      Righetti, M.C., Di Lorenzo, M.L., Angiuli, M. and Tombari, E., Macromolecules, 2004, 37: 9027

    47. [47]

      Konishi, T. and Miyamoto, Y., Macromolecules, 2010, 43: 375

    48. [48]

      Righetti, M.C. and Di Lorenzo, M.L., J. Polym. Sci., Part B: Polym. Phys., 2004, 42: 2191

    49. [49]

      Di Lorenzo, M.L. and Righetti, M.C., Polym. Bull., 2004, 53: 53

    50. [50]

      Guo, A., Yang, F. and Yu, R., Chinese J. Polym. Sci., 2015, 33(1): 23

    51. [51]

      Li, X., Chen, L., Huang, W., Li, X., Zhang, C. and Liu, X., Chinese J. Polym. Sci., 2014, 32(8): 1052

    52. [52]

      Hoffman, J.D. and Miller, R.L., Macromolecules, 1989, 22: 3502

    53. [53]

      Runt, J., Miley, D.M., Zhang, X., Gallagher, K.P., McFeaters, K. and Fishburn, J., Macromolecules, 1992, 25: 1929

    54. [54]

      Ishak, Z.A.M., Shang, P.P. and Karger-Kocsis, J., J. Therm. Anal. Calorim., 2006, 84: 637

    55. [55]

      Jandali, M.Z. and Widmann, G., Application handbook of thermal analysis: thermoplastics, Donghua University Press, Shanghai, 2008

    56. [56]

      Gupta, A.K. and Purwar, S.N., J. Appl. Polym. Sci., 1984, 29: 1595

    57. [57]

      Banks, W., Gordon, M. and Sharples, A., Polymer, 1963, 4: 289

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  • 发布日期:  2015-08-05
  • 收稿日期:  2014-11-22
  • 修回日期:  2015-01-30
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