Study on the Total Synthesis of 3-Oxo-9β-Acetoxyilicic Acid-The Synthesis of 9β-Acetoxy-3(4),11(13)-Dien-5αH,7αH-12-Eudesmanoic Acid Methyl Ester

Jiong YANG Zhao Ming XIONG Yong Gang CREN Yu Lin LI

引用本文: Jiong YANG,  Zhao Ming XIONG,  Yong Gang CREN,  Yu Lin LI. Study on the Total Synthesis of 3-Oxo-9β-Acetoxyilicic Acid-The Synthesis of 9β-Acetoxy-3(4),11(13)-Dien-5αH,7αH-12-Eudesmanoic Acid Methyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1041-1042. shu
Citation:  Jiong YANG,  Zhao Ming XIONG,  Yong Gang CREN,  Yu Lin LI. Study on the Total Synthesis of 3-Oxo-9β-Acetoxyilicic Acid-The Synthesis of 9β-Acetoxy-3(4),11(13)-Dien-5αH,7αH-12-Eudesmanoic Acid Methyl Ester[J]. Chinese Chemical Letters, 1997, 8(12): 1041-1042. shu

Study on the Total Synthesis of 3-Oxo-9β-Acetoxyilicic Acid-The Synthesis of 9β-Acetoxy-3(4),11(13)-Dien-5αH,7αH-12-Eudesmanoic Acid Methyl Ester

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China.

摘要: The synthesis of 9β-acetoxy-3(4),11(13)-dien-5αH,7αH-12-eudesmanoic acid methyl ester (2) was achieved from oxycarvone.The key step is the p-toluenesulfonhydrazide assisted reductive rearrangement reaction.

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  • 收稿日期:  1997-08-20
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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