引用本文:
Tao Wang, Shan Shi, Li Na Bian, Li Min Zhou, Li Qun Zhao, Shin Ichi Kuroda. Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure[J]. Chinese Chemical Letters,
2011, 22(12): 1505-1508.
doi:
10.1016/j.cclet.2011.06.004
Citation: Tao Wang, Shan Shi, Li Na Bian, Li Min Zhou, Li Qun Zhao, Shin Ichi Kuroda. Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure[J]. Chinese Chemical Letters, 2011, 22(12): 1505-1508. doi: 10.1016/j.cclet.2011.06.004
Citation: Tao Wang, Shan Shi, Li Na Bian, Li Min Zhou, Li Qun Zhao, Shin Ichi Kuroda. Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure[J]. Chinese Chemical Letters, 2011, 22(12): 1505-1508. doi: 10.1016/j.cclet.2011.06.004
Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure
摘要:
A series of poly (2-acetoxyethyl methacrylate)/polystyrene (PAEMA/PS) latex interpenetrating polymer networks (LIPNs) were prepared by seeded soap-free emulsion polymerization of styrene on the crosslinked PAEMA seed particles using an oil-soluble initiator. These PAEMA/PS LIPNs showed a well-defined phase-separated structure with PS phase dispersing in continuous PAEMA phase. The domain size of PS phase was found to depend on the crosslinking degree of PAEMA seed particles and the amount of second-stage styrene monomer.
English
Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure
Abstract:
A series of poly (2-acetoxyethyl methacrylate)/polystyrene (PAEMA/PS) latex interpenetrating polymer networks (LIPNs) were prepared by seeded soap-free emulsion polymerization of styrene on the crosslinked PAEMA seed particles using an oil-soluble initiator. These PAEMA/PS LIPNs showed a well-defined phase-separated structure with PS phase dispersing in continuous PAEMA phase. The domain size of PS phase was found to depend on the crosslinking degree of PAEMA seed particles and the amount of second-stage styrene monomer.
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Key words:
- Phase-separation
- / IPN
- / Seeded soap-free emulsion polymerization
- / Crosslinking
- / Particle
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