引用本文:
Wei Huang, Yu Bo Cao, Xiao Guang Zhang, Fa Sheng Li, Huai Yang. Synthesis and helical twisting property of polymerizable chiral dopant with temperature-dependent solubility in liquid crystal[J]. Chinese Chemical Letters,
2009, 20(7): 873-876.
doi:
10.1016/j.cclet.2009.03.019
Citation: Wei Huang, Yu Bo Cao, Xiao Guang Zhang, Fa Sheng Li, Huai Yang. Synthesis and helical twisting property of polymerizable chiral dopant with temperature-dependent solubility in liquid crystal[J]. Chinese Chemical Letters, 2009, 20(7): 873-876. doi: 10.1016/j.cclet.2009.03.019
Citation: Wei Huang, Yu Bo Cao, Xiao Guang Zhang, Fa Sheng Li, Huai Yang. Synthesis and helical twisting property of polymerizable chiral dopant with temperature-dependent solubility in liquid crystal[J]. Chinese Chemical Letters, 2009, 20(7): 873-876. doi: 10.1016/j.cclet.2009.03.019
Synthesis and helical twisting property of polymerizable chiral dopant with temperature-dependent solubility in liquid crystal
摘要:
In this study, right-handed dicinnamate isosorbide was synthesized via the esterification reaction between optically active isosorbide and cinnamate. The chiral dopant was characterized by FT-IR,1H NMR, elemental analysis, SEM, UV absorption spectrum. After dissolving in a nematic liquid crystal mixture, the chiral dopant exhibited a temperature-dependent solubility in the chiral nematic liquid crystal mixture. Meanwhile, a relatively high value of helical twisting power of the polymerizable chiral dopant was determined. The results show that the chiral dopant has great potential in achieving a polymer stabilized chiral nematic liquid crystal film with a broad-band selective reflection.
English
Synthesis and helical twisting property of polymerizable chiral dopant with temperature-dependent solubility in liquid crystal
Abstract:
In this study, right-handed dicinnamate isosorbide was synthesized via the esterification reaction between optically active isosorbide and cinnamate. The chiral dopant was characterized by FT-IR,1H NMR, elemental analysis, SEM, UV absorption spectrum. After dissolving in a nematic liquid crystal mixture, the chiral dopant exhibited a temperature-dependent solubility in the chiral nematic liquid crystal mixture. Meanwhile, a relatively high value of helical twisting power of the polymerizable chiral dopant was determined. The results show that the chiral dopant has great potential in achieving a polymer stabilized chiral nematic liquid crystal film with a broad-band selective reflection.
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