引用本文:
Wei Yi CHEN, Jun LU, Ya Wen ZHANG, Zong Xuan SHEN. Enantioselective Synthesis of Chiral 1-Ferrocenyl Alcohol via CBS-Reduction[J]. Chinese Chemical Letters,
2001, 12(12): 1079-1080.
Citation: Wei Yi CHEN, Jun LU, Ya Wen ZHANG, Zong Xuan SHEN. Enantioselective Synthesis of Chiral 1-Ferrocenyl Alcohol via CBS-Reduction[J]. Chinese Chemical Letters, 2001, 12(12): 1079-1080.
Citation: Wei Yi CHEN, Jun LU, Ya Wen ZHANG, Zong Xuan SHEN. Enantioselective Synthesis of Chiral 1-Ferrocenyl Alcohol via CBS-Reduction[J]. Chinese Chemical Letters, 2001, 12(12): 1079-1080.
Enantioselective Synthesis of Chiral 1-Ferrocenyl Alcohol via CBS-Reduction
摘要:
Reduction of prochiral ferrocenyl ketones 2a-e in the presence of 10 mol% of chiral β-amino alcohols 4a-b provides 1-ferrocenyl alcohols 1a-e in high yields (>85%) with high optically purity (e.e. up to 96%).
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关键词:
- β-Amino alcohol
- / chiral
- / ferrocene
- / enantioselective synthesis
- / borane
English
Enantioselective Synthesis of Chiral 1-Ferrocenyl Alcohol via CBS-Reduction
Abstract:
Reduction of prochiral ferrocenyl ketones 2a-e in the presence of 10 mol% of chiral β-amino alcohols 4a-b provides 1-ferrocenyl alcohols 1a-e in high yields (>85%) with high optically purity (e.e. up to 96%).
-
Key words:
- β-Amino alcohol
- / chiral
- / ferrocene
- / enantioselective synthesis
- / borane
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