引用本文:
Shi Guo SUN, Xiao Jun PENG, Ming Wen FAN, Yong Qian XU, Lei SHI, Li Cheng SUN. Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes[J]. Chinese Chemical Letters,
2004, 15(8): 965-968.
Citation: Shi Guo SUN, Xiao Jun PENG, Ming Wen FAN, Yong Qian XU, Lei SHI, Li Cheng SUN. Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes[J]. Chinese Chemical Letters, 2004, 15(8): 965-968.
Citation: Shi Guo SUN, Xiao Jun PENG, Ming Wen FAN, Yong Qian XU, Lei SHI, Li Cheng SUN. Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes[J]. Chinese Chemical Letters, 2004, 15(8): 965-968.
Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes
摘要:
Two novel rhenium(Ⅰ) 2,2'-bipyridyl complexes,[(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and[(4,4'-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex[(4,4'-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized.Their ground state electronic spectra and emission spectra were measured in acetonitrile.The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.
English
Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes
Abstract:
Two novel rhenium(Ⅰ) 2,2'-bipyridyl complexes,[(4,4'-di-COOEt-bipy) Re(CO)3 (NCCH3)PF6] and[(4,4'-di-COOEt-bipy) Re (CO)3 (NCS)], a model complex[(4,4'-di-COOEt-bipy) Re (CO)3 (pyridine)PF6], were synthesized.Their ground state electronic spectra and emission spectra were measured in acetonitrile.The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH3, or SCN.
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Key words:
- Rhenium(Ⅰ) 2,2'-bipyridyl complex
- / photosensitizer
- / red shift
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