The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation

Hai Tao Xi Tian Tian Yi Xiao Qiang Sun

引用本文: Hai Tao Xi,  Tian Tian Yi,  Xiao Qiang Sun. The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation[J]. Chinese Chemical Letters, 2010, 21(6): 633-636. doi: 10.1016/j.cclet.2010.01.028 shu
Citation:  Hai Tao Xi,  Tian Tian Yi,  Xiao Qiang Sun. The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation[J]. Chinese Chemical Letters, 2010, 21(6): 633-636. doi: 10.1016/j.cclet.2010.01.028 shu

The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation

  • 基金项目:

    We acknowledge financial support from the National Natural Science Foundation of China (No. 20872051).

摘要: Two novel fluorine-containing cyclophanes 1 and 2 incorporating a 1,4-bismethylfluorophenylene subunits have been synthesized via the template-directed clipping methodology and their structure was characterized by 1H NMR, 13C NMR, MALDI-TOF-MS and elemental analysis. X-ray diffraction analysis of the solid state molecular structure showed that the complex units are linked by non-classical C-H…F hydrogen bonding.

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  • 收稿日期:  2009-11-03
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