Synthesis of Well-Defined Dendritic-Linear Diblock and Triblock Copolymers by Controlled Free Radical Polymerization

You Liang ZHAO Chuan Fu CHEN Fu XI

引用本文: You Liang ZHAO,  Chuan Fu CHEN,  Fu XI. Synthesis of Well-Defined Dendritic-Linear Diblock and Triblock Copolymers by Controlled Free Radical Polymerization[J]. Chinese Chemical Letters, 2002, 13(3): 217-218. shu
Citation:  You Liang ZHAO,  Chuan Fu CHEN,  Fu XI. Synthesis of Well-Defined Dendritic-Linear Diblock and Triblock Copolymers by Controlled Free Radical Polymerization[J]. Chinese Chemical Letters, 2002, 13(3): 217-218. shu

Synthesis of Well-Defined Dendritic-Linear Diblock and Triblock Copolymers by Controlled Free Radical Polymerization

摘要: The design and synthesis of novel dendritic-linear block copolymers were described. The copolymers were synthesized by atom transfer radical polymerization (ATRP) using dendritic polyarylether 2-bromoisobutyrate macroinitiator. ATRP carried out in bulk with CuBr/bipy catalyst at 120℃, yielded well-defined block copolymers with polydispersities less than 1.36.

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  • 收稿日期:  2001-08-17
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