引用本文:
Jing Chao TAO, Jun JIA, Xing Wang WANG, Song Tao ZANG. Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Cyclopalladated Ferrocenylketimines[J]. Chinese Chemical Letters,
2002, 13(12): 1170-1173.
Citation: Jing Chao TAO, Jun JIA, Xing Wang WANG, Song Tao ZANG. Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Cyclopalladated Ferrocenylketimines[J]. Chinese Chemical Letters, 2002, 13(12): 1170-1173.
Citation: Jing Chao TAO, Jun JIA, Xing Wang WANG, Song Tao ZANG. Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Cyclopalladated Ferrocenylketimines[J]. Chinese Chemical Letters, 2002, 13(12): 1170-1173.
Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Cyclopalladated Ferrocenylketimines
摘要:
In this paper, four functional substituted derivatives of cyclopalladated ferrocenylketimines 1~4, which were as mimetics of metal-dependent esterases for catalyzing the hydrolysis of thiophosphoric acid esters pesticides, were synthesized and characterized. All the four cyclopalladated complexes can efficiently catalyze the degradation of thiophosphoric acid pesticides, such as methyl parathion. The Pd catalyst with coordinated oxime is more active and exhibits an increased selectivity towards sulfur containing pesticides.
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关键词:
- Ferrocenylketimine
- / cyclopalladation
- / thiophosphate
- / catalysis
English
Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Cyclopalladated Ferrocenylketimines
Abstract:
In this paper, four functional substituted derivatives of cyclopalladated ferrocenylketimines 1~4, which were as mimetics of metal-dependent esterases for catalyzing the hydrolysis of thiophosphoric acid esters pesticides, were synthesized and characterized. All the four cyclopalladated complexes can efficiently catalyze the degradation of thiophosphoric acid pesticides, such as methyl parathion. The Pd catalyst with coordinated oxime is more active and exhibits an increased selectivity towards sulfur containing pesticides.
-
Key words:
- Ferrocenylketimine
- / cyclopalladation
- / thiophosphate
- / catalysis
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