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Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

LU Jiu-Fu ,  SHI Juan ,  ZHENG Nan ,  GUO Xiao-Hua ,  GE Hong-Guang

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Citation:  LU Jiu-Fu, SHI Juan, ZHENG Nan, GUO Xiao-Hua, GE Hong-Guang. Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework[J]. Chinese Journal of Structural Chemistry, 2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814 shu

Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework

  • 1.

    Chemical Engineering College, Shaanxi University of Technology, Hanzhong 723001, China

  • 基金项目:

    This project was supported by the National Natural Science Foundation of China (No. 21373132)  (No. 21373132)

    the Foundation of Shaanxi university of technology (No. SLGKY15-36) (No. SLGKY15-36)

摘要: A new coordination polymer, {[Ag2(bpp)2(H2O)2]·bpdc·3H2O}n, derived from the ligand biphenyl-4,4'-dicarboxylic acid (H2bpdc), has been obtained through a hydrothermal technique (bpp = 1,3-bis(4-pyridyl)propane). Its single-crystal structure has been characterized by single-crystal X-ray diffraction, powder XRD, FT-IR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains, 2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal structure. The 1D infinite [Ag(bpp)(H2O)]nn+ cationic chains and 2D anionic layer are further stacked in -ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like framework. In addition, the luminescent property of complex 1 in the solid state at room temperature was investigated.

English

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  • 收稿日期:  2015-05-19
  • 网络出版日期:  2015-07-20
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