引用本文:
刘胜生, 于广谦, 黄葆同. 茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的13C NMR研究[J]. 应用化学,
1996, 13(4): 110-112.
Citation: Liu Shengsheng, Yu Guangqian, Huang Baotong. Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the 13C NMR Analysis of Copolymers[J]. Chinese Journal of Applied Chemistry, 1996, 13(4): 110-112.
Citation: Liu Shengsheng, Yu Guangqian, Huang Baotong. Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the 13C NMR Analysis of Copolymers[J]. Chinese Journal of Applied Chemistry, 1996, 13(4): 110-112.
茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的13C NMR研究
English
Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the 13C NMR Analysis of Copolymers
Abstract:
Copolymerization of ethylene/octene-1 was investigated by using two types of supported zirconocene catalysts, Zr/MAO/SiO2 and Zr/MAO/SAA,where SiO2 and poly(styrene-acrylamide) (SAA) were used as carriers respectively. The results showed that the catalysts have high copolymerization ability. The triad sequence distribution and mean sequence lengths of monomers in the copolymers have been calculated by 13C NMR data.
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Key words:
- supported zirconocene catalyst
- / copolymerization
- / sequence distribution
- / 13C NMR
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