引用本文:
黄金满, 杨梅林, 沈家骢, 杨冰. 自由基聚合反应物相对分子质量分布的计算[J]. 应用化学,
1996, 13(4): 41-44.
Citation: Huang Jinman, Yang Meilin, Shen Jiacong, Yang Bing. Calculation of the Relative Molecular Mass Distribution Functions of Free Radical Polymerization[J]. Chinese Journal of Applied Chemistry, 1996, 13(4): 41-44.
Citation: Huang Jinman, Yang Meilin, Shen Jiacong, Yang Bing. Calculation of the Relative Molecular Mass Distribution Functions of Free Radical Polymerization[J]. Chinese Journal of Applied Chemistry, 1996, 13(4): 41-44.
自由基聚合反应物相对分子质量分布的计算
摘要:
结合隐函数和Monte Carlo方法,给出了自由基聚会反应物相对分子质量分布函数的可计算解的形式.分析积分函数的性质,确定了有效积分区间,提高了计算速度,给出苯乙烯本体聚合反应物相对分子质量分布的理论计算结果,与实验结论一致.
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关键词:
- 自由基聚合反应
- / 有效积分域
- / 相对分子质量
- / 分布Monte Carlo方法
- / GPC
English
Calculation of the Relative Molecular Mass Distribution Functions of Free Radical Polymerization
Abstract:
The solutions of relative molecular mass distribution functions for free radical polymerizations are given in terms of implicit functions and by use of Monte Carlo method. After analyzing the properties of the integrals,the effective integration area for the solution equations is established,so the speed of calculation is increased. Theoretical data for the relative molecular mass distribution of styrene bulk polymerization have been obtained in good agreement with experimental results.
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