静电纺丝方法制备CaTiO<sub>3</sub>:Er<sup>3+</sup>微米带及其上转换发光性质

引用本文: 彭冲, 杨冬梅, 李国岗, 连洪州, 林君. 静电纺丝方法制备CaTiO₃:Er³⁺微米带及其上转换发光性质[J]. 应用化学, 2012, 29(12): 1438-1446. doi: 10.3724/SP.J.1095.2012.20429 shu

Citation: PENG Chong, YANG Dongmei, LI Guogang, LIAN Hongzhou, LIN Jun. Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO₃: Er³⁺ Microbelts[J]. Chinese Journal of Applied Chemistry, 2012, 29(12): 1438-1446. doi: 10.3724/SP.J.1095.2012.20429 shu

静电纺丝方法制备CaTiO₃:Er³⁺微米带及其上转换发光性质

彭冲 ^a,b, ,
杨冬梅 ^a,b, ,
李国岗 ^a,b, ,
连洪州 ^a, ,
林君 ^{a,
,}

1.
a 中国科学院长春应用化学研究所, 稀土资源利用国家重点实验室长春 130022;
2.
b 中国科学院大学北京 100049

通讯作者: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

摘要: CaTiO₃:Er³⁺微米带由静电纺丝方法制备。用X射线衍射、傅里叶变换红外光谱、拉曼光谱、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)和上转换发光表征所制备的样品。SEM和TEM测试证实所得前躯体微米带尺寸均一,烧后得到的微米带是由纳米粒子组成的。在980 nm激光激发下,CaTiO₃:Er³⁺样品发出绿光,绿光发射峰位于546 nm,可归属于Er³⁺离子的⁴S_3/2→⁴I_15/2跃迁。当Er³⁺离子的掺杂浓度提高,因为Er³⁺离子之间的能量传递,红光发射相对于绿光发射增强。

关键词:

上转换
/ 静电纺丝
/ 微米带
/ 铒

English

Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO₃: Er³⁺ Microbelts

1.
a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

Received Date: 26 September 2012

Abstract: One-dimensional CaTiO₃:Er³⁺ microbelts have been prepared by electrospinning method.X-ray diffraction,Fourier transform infrared spectroscopy,Raman spectroscopy,scanning electron microscopy(SEM),transmission electron microscopy(TEM),high-resolution transmission electron microscopy(HRTEM),up-converted luminescence were used to characterize the resulting samples.SEM and TEM analysis indicate that the obtained precursor belts have a uniform size,and the as-formed microbelts consist of nanoparticles.Under 980 nm laser beam excitation,the CaTiO₃:Er³⁺ samples exhibit a green emission band with a maximum at 546 nm originating from the ⁴S_3/2→⁴I_15/2 transitions of Er³⁺ ions.When the Er³⁺ concentration increases,the red emission of CaTiO₃:Er³⁺ increases relative to the green emission,which is due to the energy transfer between Er³⁺ ions.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

静电纺丝方法制备CaTiO₃:Er³⁺微米带及其上转换发光性质

通讯作者: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

English

Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO₃: Er³⁺ Microbelts

Corresponding author: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

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通讯作者: 陈斌, bchen63@163.com

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静电纺丝方法制备CaTiO3:Er3+微米带及其上转换发光性质

通讯作者: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

English

Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO3: Er3+ Microbelts

Corresponding author: LIN Jun, professor; Tel:0431-85262031; Fax:0431-85698041; E-mail:jlin@ciac.jl.cn; Research Interests:luminescent materials

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

静电纺丝方法制备CaTiO₃:Er³⁺微米带及其上转换发光性质

Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO₃: Er³⁺ Microbelts

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs