引用本文:
安玉馨, 丁孟贤. 施光性高分子——聚(对-乙烯基-α-甲基苯甲醇)的合成[J]. 应用化学,
1985, 2(2): 69-71.
Citation: An Yuxin, Ding Mengxian. SYNTHESIS OF OPTICALLY ACTIVE POLY(P-VINYL-α-METHYLBENZYL ALCOHOL)[J]. Chinese Journal of Applied Chemistry, 1985, 2(2): 69-71.
Citation: An Yuxin, Ding Mengxian. SYNTHESIS OF OPTICALLY ACTIVE POLY(P-VINYL-α-METHYLBENZYL ALCOHOL)[J]. Chinese Journal of Applied Chemistry, 1985, 2(2): 69-71.
施光性高分子——聚(对-乙烯基-α-甲基苯甲醇)的合成
摘要:
七十年代以前,旋光性高分子的研究主要着眼于聚合反应本身,即企图借助旋光性单体获得立体规整聚合物,或使用手性引发剂,Ziegler-Natta型催化剂等由潜手性单体聚合以得到旋光性高分子[1]。近十多年来,对于旋光性高分子的兴趣逐渐转到其可能的应用方面,如用做色谱法直接拆分的手性固定相及用于不对称合成的高分子化手性试剂或催化剂等。
English
SYNTHESIS OF OPTICALLY ACTIVE POLY(P-VINYL-α-METHYLBENZYL ALCOHOL)
Abstract:
The optically active p-vinyl-α-methylbenzyl alcohol obtained from p-vinyl acetophenone via asymmetric reduction using (S)-2-anilinomethylpyrrolidine-LiAlH4 as a chiral reagent was polymerised to the poly(p-vinyl-α-methylbenzyl alcohol). The optical purity of the chiral polymer was found to be 61.5%.
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