由1,4-双(咪唑-1-基)丁烷配体和2,5-噻吩二羧酸构筑的镉配合物的合成、结构和性质研究

李佳 ,  刘博

引用本文: 李佳, 刘博. 由1,4-双(咪唑-1-基)丁烷配体和2,5-噻吩二羧酸构筑的镉配合物的合成、结构和性质研究[J]. 化学通报, 2016, 79(11): 1085-1088. shu
Citation:  Li Jia, Liu Bo. Syntheses, Crystal Structure and Properties of a Cadmium Complex containing 2, 5-Thiophene Dicarboxylic Acid and 1, 1'-(1, 4-Butanediyl)Bis(imidazole)[J]. Chemistry, 2016, 79(11): 1085-1088. shu

由1,4-双(咪唑-1-基)丁烷配体和2,5-噻吩二羧酸构筑的镉配合物的合成、结构和性质研究

摘要: 常温下,以溶液法合成了一个单核结构的镉配合物[Cd(bbi)(tdc)(H2O)]n·nH2O (bbi:1,4-双(咪唑-1-基)丁烷;H2tdc:2,5-噻吩二羧酸),通过单晶X-射线衍射、红外光谱、元素分析对其进行了结构表征,并研究了配合物的热稳定性和荧光性质。配合物属于正交晶系,空间群Fdd2,晶胞参数:a=20.945(2)Å,b=32.309(4)Å,c=12.1084(14)Å,α=90°,β=90°,γ=90°,V=8194.1(16)Å3,C16H20CdN4O6S,Mr=508.82,Z=16,Dc=1.650 g·cm-3,F(000)=4096,R1=0.0186,wR2=0.0491。来自tdc配体的羧基氧原子与Cd离子配位形成1D直线型链,并通过含氮配体bbi与Cd离子配位最终形成了3D结构。

English

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  • 收稿日期:  2016-05-13
  • 网络出版日期:  2016-06-20
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