引用本文:
顾修君, 钟顺和. 1,2-二氯丙烷加氢脱氯制丙烯Ni/活化炭化树脂催化剂[J]. 应用化学,
1999, 16(6): 5-8.
Citation: Gu Xiujun, Zhong Shunhe. Hydrodechlorination of 1, 2-Dichloropropane to Propene over Carbonized Resin Supported Nickel Catalyst[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 5-8.
Citation: Gu Xiujun, Zhong Shunhe. Hydrodechlorination of 1, 2-Dichloropropane to Propene over Carbonized Resin Supported Nickel Catalyst[J]. Chinese Journal of Applied Chemistry, 1999, 16(6): 5-8.
1,2-二氯丙烷加氢脱氯制丙烯Ni/活化炭化树脂催化剂
English
Hydrodechlorination of 1, 2-Dichloropropane to Propene over Carbonized Resin Supported Nickel Catalyst
Abstract:
The carbonized resin support has been prepared.The Ni catalysts have been prepared by isometric impregnation of Ni(NO3)2 solution with carbonized resin support using ethylenediamine as solvent.Their superficial structures have been characterized by BET, SEM, XRD and TEM techniques.The reaction behavior of Ni supported on the carbonized resin in hydrodechlorination of 1, 2-dichloropropane to propene have been evaluated in a microreactor.The results show that the carbonized resin after activation has a specific area of 611 m2/g, the nickel supported on the resin has an average crystal size of 30 um and distributes uniformly.Over the activated carbonized resin supported nickel catalyst for hydrodechlorination of 1, 2-dichloropropane the latter has conversion more than 68% with the selectivity to propene being 100% under proper reaction conditions.
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Key words:
- dichloropropane
- / hydrodechlorination
- / propene
- / activated carbonized resin support
- / nickel catalyst
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