引用本文:
陈成, 彭树文, 费宾, 安玉贤, 庄宇刚, 董丽松, 冯之榴. 聚β-羟基丁酸酯接枝顺丁烯二酸酐的研究[J]. 应用化学,
2001, 18(1): 12-15.
Citation: CHEN Cheng, PENG Shu-Wen, FEI Bin, AN Yu-Xian, ZHUANG Yu-Gang, DONG Li-Song, FENG Zhi-Liu. Study on the Free Radical Graft Copolymerization of Maleic Anhydride onto Poly(β-hydroxybutyrate)[J]. Chinese Journal of Applied Chemistry, 2001, 18(1): 12-15.
Citation: CHEN Cheng, PENG Shu-Wen, FEI Bin, AN Yu-Xian, ZHUANG Yu-Gang, DONG Li-Song, FENG Zhi-Liu. Study on the Free Radical Graft Copolymerization of Maleic Anhydride onto Poly(β-hydroxybutyrate)[J]. Chinese Journal of Applied Chemistry, 2001, 18(1): 12-15.
聚β-羟基丁酸酯接枝顺丁烯二酸酐的研究
English
Study on the Free Radical Graft Copolymerization of Maleic Anhydride onto Poly(β-hydroxybutyrate)
Abstract:
The graft copolymerization of maleic anhydride(MA) onto poly(U-hydro-xybutyrate) (PHB) using benzoyl peroxide as initiator was studied. The effects of polymerization conditions on graft degree,including solvents, monomer and initiator concentrations, reaction temperature and time,were investigated. The best reaction conditions were described. The results showed that graft degree of MA onto PHB could be controlled in the range from 0.3% to 0.85%. The grafted PHB was characterized by 13C NMR and chemical titration of MA group.
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Key words:
- poly(U-hydroxybutyrate)
- / maleic anhydride
- / graft copolymerization
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