引用本文:
朱宁, 唐涛, 陈辉, 于广谦, 冯之榴, 黄葆同. 有机/无机纳米杂化材料载体化钛催化剂的聚合研究Ⅱ.间同聚苯乙烯制备[J]. 应用化学,
2001, 18(1): 9-11.
Citation: ZHU Ning, TANG Tao, CHEN Hui, YU Guang-Qian, FENG Zhi-Liu, HUANG Bao-Tong. Study on the Polymerization with Organic/Inorganic Hybrid-Supported Titanium Catalysts Ⅱ.Styrene Polymerizaton[J]. Chinese Journal of Applied Chemistry, 2001, 18(1): 9-11.
Citation: ZHU Ning, TANG Tao, CHEN Hui, YU Guang-Qian, FENG Zhi-Liu, HUANG Bao-Tong. Study on the Polymerization with Organic/Inorganic Hybrid-Supported Titanium Catalysts Ⅱ.Styrene Polymerizaton[J]. Chinese Journal of Applied Chemistry, 2001, 18(1): 9-11.
有机/无机纳米杂化材料载体化钛催化剂的聚合研究Ⅱ.间同聚苯乙烯制备
English
Study on the Polymerization with Organic/Inorganic Hybrid-Supported Titanium Catalysts Ⅱ.Styrene Polymerizaton
Abstract:
The use of organic/inorganic hybrid materials poly(styrene-co-maleic anhydride)/SiO2 as the support for titanium catalysts in styrene polymerization was studied. Results indicated that at 70℃ the activity of the inorganic/organic hybrid supported catalysts would reached a maximum; 1.49×106 g/(mol·h). With increase in reaction temperature, the molecular weight of polymer decreased, and the polydispersity was much wider. DSC and FTIR measurements showed that the product was syndiotatic polystyrene.
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