引用本文:
韩杰, 支永刚, 张良辅. 二氮杂环庚酮及其烷氧亚氨基衍生物的合成[J]. 应用化学,
2001, 18(7): 572-574.
Citation: HAN Jie, ZHI Yong-Gang, ZHANG Liang-Fu. Syntheses of Diazacycloheptanone and Its Alkoxyimine Derivatives[J]. Chinese Journal of Applied Chemistry, 2001, 18(7): 572-574.
Citation: HAN Jie, ZHI Yong-Gang, ZHANG Liang-Fu. Syntheses of Diazacycloheptanone and Its Alkoxyimine Derivatives[J]. Chinese Journal of Applied Chemistry, 2001, 18(7): 572-574.
二氮杂环庚酮及其烷氧亚氨基衍生物的合成
English
Syntheses of Diazacycloheptanone and Its Alkoxyimine Derivatives
Abstract:
N,N'-Ditosyl-1,5-diazacycloheptan-3-one(2) and its derivatives(3b~3d) have been synthesized from 1,3-dichloro-2-propanol and N,N'-ditosylethylenediamine via cyclization, oxidation and substitution.All the new compounds(2 and 3a~3d) have been characterized by IR, 1H NMR, MS and elemental analysis.The reactions of all steps are carried out under moderate conditions with the overall yield 27%~30%.
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Key words:
- diazacycloheptanone
- / oxime
- / synthesis
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