引用本文:
李人宇, 卑凤利, 杨绪杰, 许兴友, 陆路德, 汪信. N-(4-羟基苯基亚甲基)-1-萘胺的室温固相合成、表征及晶体结构[J]. 应用化学,
2003, 20(9): 911-913.
Citation: LI Ren-Yu, BEI Feng-Li, YANG Xu-Jie, XU Xing-You, LU Lu-De, WANG Xin. Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine[J]. Chinese Journal of Applied Chemistry, 2003, 20(9): 911-913.
Citation: LI Ren-Yu, BEI Feng-Li, YANG Xu-Jie, XU Xing-You, LU Lu-De, WANG Xin. Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine[J]. Chinese Journal of Applied Chemistry, 2003, 20(9): 911-913.
N-(4-羟基苯基亚甲基)-1-萘胺的室温固相合成、表征及晶体结构
摘要:
Schiff碱及其配合物具有杀菌抗病毒[1]、可逆结合氧气[2]、非线性光学[3]、磁性[4]、仿酶催化[5]等一系列优良性能。Schiff碱传统上的溶液合成方法,需要有机溶剂和加热[6]。室温或低热固相反应具有无溶剂、节能、产率高、污染少、选择性好、操作简单等优点,作为一种绿色的化学合成方法日益受到重视[7]。
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关键词:
- N-(羟基苯基亚甲基)萘胺
- / Schiff碱
- / 固相反应
- / 晶体结构
English
Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine
Abstract:
N-(4-Hydroxyphenylmethylene)-1-naphthylamine was synthesized by the solid phase reaction of 1-naphthylamine and 4-hydroxybenzaldehyde at room temperature. The reaction was completed in 15 min in yield of 95%. The product was characterized by elemental analysis, IR, X-ray powder diffractometry and 1H NMR. The crystal as determined by X-ray single crystal diffractometry belongs to monoclinic system with space group P21/c, a=1.004 9(2), b=1.047 3(2), c=1.200 2(2) nm, β=92.60(3)°, V=1.261 8(4) nm3, Dc=1.302 g/cm3, Z=4, F(000)=528, μ=0.081 mm-1, R=0.0375, wR=0.106 2, S=1.024.
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