引用本文:
赫泓, 龚剑, 陈亚光, 瞿伦玉. 多金属氧酸盐掺杂聚苯胺电子聚合物——多金属氧酸盐与HCl共掺杂聚苯胺HCl-SiW11Co/PAn的合成及其性质[J]. 应用化学,
2006, 23(5): 533-537.
Citation: HE Hong, GONG Jian, CHEN Ya-Guang, QU Lun-Yu. Functional Polyaniline Doped with Polyoxometalate——Synthesis and Characterization of SiW11Co/PAn by Co-insertion of HCl and Polyoxometalate[J]. Chinese Journal of Applied Chemistry, 2006, 23(5): 533-537.
Citation: HE Hong, GONG Jian, CHEN Ya-Guang, QU Lun-Yu. Functional Polyaniline Doped with Polyoxometalate——Synthesis and Characterization of SiW11Co/PAn by Co-insertion of HCl and Polyoxometalate[J]. Chinese Journal of Applied Chemistry, 2006, 23(5): 533-537.
多金属氧酸盐掺杂聚苯胺电子聚合物——多金属氧酸盐与HCl共掺杂聚苯胺HCl-SiW11Co/PAn的合成及其性质
English
Functional Polyaniline Doped with Polyoxometalate——Synthesis and Characterization of SiW11Co/PAn by Co-insertion of HCl and Polyoxometalate
Abstract:
SiW11Co/Polyaniline(PAn) was synthesized by co-insertion of HCl together with substituted heteropolyanion.Its thermal stability,fluorescence property,conductivity,cyclic voltammetric behavior and magnetism were investigated.The results revealed that SiW11Co/PAn had better thermal stability.Its decomposition temperature is about 162℃ higher than that of PAn base.The conductivity of the material is 0.54 S/cm.It has reversible electrochemical property.Its saturation magnetization is higher than that of the heteropolyacid,and at the same time,the system shows paramagnetism.
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Key words:
- polyaniline
- / polyoxometalate
- / doping
- / fluorescence
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