注册 English

两个含2,4-二氯苯氧乙酸及氮杂环配体的Ag(Ⅰ)配合物的合成及晶体结构

郝晓敏 ,  谷长生 ,  纪丽丽 ,  李世杰 ,  李泳 ,  宋文东

downloadPDF
引用本文: 郝晓敏, 谷长生, 纪丽丽, 李世杰, 李泳, 宋文东. 两个含2,4-二氯苯氧乙酸及氮杂环配体的Ag(Ⅰ)配合物的合成及晶体结构[J]. 无机化学学报, 2015, (5): 1063-1070. doi: 10.11862/CJIC.2015.143 shu
Citation:  HAO Xiao-Min, GU Chang-Sheng, JI Li-Li, LI Shi-Jie, LI Yong, SONG Wen-Dong. Syntheses and Crystal Structures of Two Ag(Ⅰ) Complexes with 2,4-Dichlorophenoxyacetic Acid and Nitrogen Heterocyclic Ligands[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 1063-1070. doi: 10.11862/CJIC.2015.143 shu

两个含2,4-二氯苯氧乙酸及氮杂环配体的Ag(Ⅰ)配合物的合成及晶体结构

  • 1.

    1 广东海洋大学理学院, 湛江 524088;

  • 2.

    2 浙江海洋学院创新应用学院, 舟山 316022

    • 通讯作者: 谷长生 gcsheng1968@126.com, 宋文东 swd60@163.com; 谷长生 gcsheng1968@126.com, 宋文东 swd60@163.com
  • 基金项目:

    广东省自然科学基金(No.S2012020011054) (No.S2012020011054)

    2011年省部产学研结合引导项目(No.102011B090400415) (No.102011B090400415)

    2011年度湛江市第八批科技攻关计划项目(No.2011C3108001)资助。 (No.2011C3108001)

摘要: 以2,4-二氯苯氧乙酸、2,2'-联吡啶、4,4'-联吡啶和硝酸银为原料,采用自然挥发法制备了2个配合物{[Ag2(ELBA)(4,4'-bipy)2(NO3)]·2H2O}n(1)和[Ag2(ELBA)2(2,2'-bipy)]n(2)(ELBA=2,4-二氯苯氧乙酸,4,4'-bipy=4,4'-联吡啶,2,2'-bipy=2,2'-联吡啶),并对其进行了元素分析、红外光谱、热稳定性和X-射线单晶衍射的表征,研究了配合物2的荧光性质。结果表明,配合物1和2均为一维结构,其中,配合物1是通过4,4'-联吡啶和银离子间的作用形成梯状结构;而配合物2是通过Ag…Ag作用构筑S状结构。配合物中存在氢键和π-π堆积等弱的分子间作用力。

English

  • 

    1. [1] Li J R, Ma Y, Mccarthy M C, et al. Coord. Chem. Rev., 2011,255:1791-1823[1] Li J R, Ma Y, Mccarthy M C, et al. Coord. Chem. Rev., 2011,255:1791-1823

    2. [2] Martínez C, Corma A. Coord. Chem. Rev., 2011,255:1558-1580[2] Martínez C, Corma A. Coord. Chem. Rev., 2011,255:1558-1580

    3. [3] Hinterholzinger F M, Ranft A, Feckl J M, et al. J. Mater. Chem., 2012,22:10356-10362[3] Hinterholzinger F M, Ranft A, Feckl J M, et al. J. Mater. Chem., 2012,22:10356-10362

    4. [4] Zhang Z Y, Deng Z P, Huo L H, et al. Inorg. Chem., 2013, 52:5914-5923[4] Zhang Z Y, Deng Z P, Huo L H, et al. Inorg. Chem., 2013, 52:5914-5923

    5. [5] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48: 2873-2879[5] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48: 2873-2879

    6. [6] Yam V W W, Lo K K W. Chem. Soc. Rev., 1999,28:323-334[6] Yam V W W, Lo K K W. Chem. Soc. Rev., 1999,28:323-334

    7. [7] Wang Y L, Liu Q Y, Xu L. CrystEngComm, 2008,10:1667-1673[7] Wang Y L, Liu Q Y, Xu L. CrystEngComm, 2008,10:1667-1673

    8. [8] Deng Z P, Huo L H, Li M S, et al. Cryst. Growth Des., 2011, 11:3090-3100[8] Deng Z P, Huo L H, Li M S, et al. Cryst. Growth Des., 2011, 11:3090-3100

    9. [9] Deng Z P, Qi H L, Huo L H, et al. CrystEngComm, 2011,13: 6632-6642[9] Deng Z P, Qi H L, Huo L H, et al. CrystEngComm, 2011,13: 6632-6642

    10. [10] HAO Xiao-Min(郝晓敏), GU Chang-Sheng(谷长生), HAN Si-Yin(韩丝银), et al. Chinese. J. Struct. Chem.(结构化学), 2015,34(3):408-416[10] HAO Xiao-Min(郝晓敏), GU Chang-Sheng(谷长生), HAN Si-Yin(韩丝银), et al. Chinese. J. Struct. Chem.(结构化学), 2015,34(3):408-416

    11. [11] YANG Ying-Qun(杨颖群), LI Chang-Hong(李昶红), LI Wei (李薇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(9):1531-1534[11] YANG Ying-Qun(杨颖群), LI Chang-Hong(李昶红), LI Wei (李薇), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(9):1531-1534

    12. [12] Gu C S, Hao X M, Guan S X, et al. Acta Cryst. C, 2006,62 (11):516-518[12] Gu C S, Hao X M, Guan S X, et al. Acta Cryst. C, 2006,62 (11):516-518

    13. [13] Shi S M, Chen Z F, Liu Y C, et al. J. Coord. Chem., 2008, 61:2725-2734[13] Shi S M, Chen Z F, Liu Y C, et al. J. Coord. Chem., 2008, 61:2725-2734

    14. [14] Feng Q, Yan M J, Wu L L, et al. Inorg. Chem. Commun., 2014,43:1-4[14] Feng Q, Yan M J, Wu L L, et al. Inorg. Chem. Commun., 2014,43:1-4

    15. [15] WANG Zhi-Yong(王志勇), WANG Wei-Min(王卫民), LI Gang(李刚). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(2):366-370[15] WANG Zhi-Yong(王志勇), WANG Wei-Min(王卫民), LI Gang(李刚). Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(2):366-370

    16. [16] Sheldrick G M. SADABS, Siemens Area Detector Absorption Corrected Software, University of Göttingen, Germany, 1996.[16] Sheldrick G M. SADABS, Siemens Area Detector Absorption Corrected Software, University of Göttingen, Germany, 1996.

    17. [17] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.[17] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.

    18. [18] Tong M L, Wu Y M, Ru J, et al. Inorg. Chem., 2002,41: 4846-4848[18] Tong M L, Wu Y M, Ru J, et al. Inorg. Chem., 2002,41: 4846-4848

    19. [19] Gao S, Liu J W, Huo L H, et al. Inorg. Chem. Comm., 2005, 8:361-364[19] Gao S, Liu J W, Huo L H, et al. Inorg. Chem. Comm., 2005, 8:361-364

    20. [20] LIU Dao-Sen(刘道森), LIANG Fa-Ku(梁法库), WANG Zhi-Wu(王志武). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(9):2007-2012[20] LIU Dao-Sen(刘道森), LIANG Fa-Ku(梁法库), WANG Zhi-Wu(王志武). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(9):2007-2012

    21. [21] HAO Xiao-Min(郝晓敏), GU Chang-Sheng(谷长生), HAN Si-Yin(韩丝银), et al. Chinese J. Inorg. Chem.(无机化学学 报), 2015,31(2):369-376[21] HAO Xiao-Min(郝晓敏), GU Chang-Sheng(谷长生), HAN Si-Yin(韩丝银), et al. Chinese J. Inorg. Chem.(无机化学学 报), 2015,31(2):369-376

    22. [22] WENG Shi-Fu(翁诗甫). Fourier Translation Infrared Spectr-oscopy. 2nd Ed.(傅里叶变换红外光谱分析.2版). Beijing: Chemical industry Press, 2010.[22] WENG Shi-Fu(翁诗甫). Fourier Translation Infrared Spectr-oscopy. 2nd Ed.(傅里叶变换红外光谱分析.2版). Beijing: Chemical industry Press, 2010.

    23. [23] Mürsel A, Okan Z Y, Seda K, et al. Polyhedron, 2012,45: 103-106[23] Mürsel A, Okan Z Y, Seda K, et al. Polyhedron, 2012,45: 103-106

    24. [24] ZHAO Xiu-Hua(赵秀华), ZHAO Ya-Yun(赵亚云), ZHANG Jie(张洁), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(3):633-639[24] ZHAO Xiu-Hua(赵秀华), ZHAO Ya-Yun(赵亚云), ZHANG Jie(张洁), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(3):633-639

    25. [25] Zhou Y H, Tian Y P. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2010,40:734-738[25] Zhou Y H, Tian Y P. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2010,40:734-738

    26. [26] Li X, Wang X W, Zhang Y H. Inorg. Chem. Commun., 2008, 11:832-834[26] Li X, Wang X W, Zhang Y H. Inorg. Chem. Commun., 2008, 11:832-834

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  950
  • HTML全文浏览量:  56
文章相关
  • 收稿日期:  2015-01-18
  • 网络出版日期:  2015-03-22
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net