注册 English

芳基取代茚基钌羰基化合物的合成及晶体结构

马志宏 ,  刘英春 ,  李素贞 ,  韩占刚 ,  郑学忠 ,  林进

downloadPDF
引用本文: 马志宏, 刘英春, 李素贞, 韩占刚, 郑学忠, 林进. 芳基取代茚基钌羰基化合物的合成及晶体结构[J]. 无机化学学报, 2015, (5): 1049-1054. doi: 10.11862/CJIC.2015.140 shu
Citation:  MA Zhi-Hong, LIU Ying-Chun, LI Su-Zhen, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Ruthenium Carbonyl Complexes Involving Aryl-Substituted Indenyl Ligands: Syntheses and Structures[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 1049-1054. doi: 10.11862/CJIC.2015.140 shu

芳基取代茚基钌羰基化合物的合成及晶体结构

  • 1.

    1 河北师范大学化学与材料科学学院, 石家庄 050024;

  • 2.

    2 河北医科大学基础医学院, 石家庄 050017;

  • 3.

    3 河北工业职业技术学院, 石家庄 050091

    • 通讯作者: 林进 linjin64@126.com
  • 基金项目:

    国家自然科学基金(No.21372061) (No.21372061)

    河北省自然科学基金(No.B2013205025,B2014205018) (No.B2013205025,B2014205018)

    河北师范大学重点基金(No.L2012Z02)资助项目。 (No.L2012Z02)

摘要: 配体C9H7R(R=Ph(1),4-tolyl(2),4-chlorophenyl(3),4-methoxyphenyl(1),2-thienyl(5))分别与Ru3(CO)12在甲苯或二甲苯中加热回流,得到了5个双核配合物[(η5-C9H6R)Ru(CO)]2(μ-CO)2(R=Ph(6),4-tolyl(7),4-chlorophenyl(8),4-methoxyphenyl(9),2-thienyl(10))。通过元素分析、红外光谱、核磁共振氢谱对配合物的结构进行了表征,并用X-射线单晶衍射法测定了配合物6,7和10的结构。

English

    1. [1] Cadierno V, Díez J, Gamasa M P, et al. Coord. Chem. Rev., 1999,193-195:147-205[1] Cadierno V, Díez J, Gamasa M P, et al. Coord. Chem. Rev., 1999,193-195:147-205

    2. [2] Calhorda M J, Félix V, Veiros L F. Coord. Chem. Rev., 2002, 230:49-64[2] Calhorda M J, Félix V, Veiros L F. Coord. Chem. Rev., 2002, 230:49-64

    3. [3] Zargarian D. Coord. Chem. Rev., 2002,233-234:157-176[3] Zargarian D. Coord. Chem. Rev., 2002,233-234:157-176

    4. [4] Halterman R L. Chem. Rev., 1992,92:965-994[4] Halterman R L. Chem. Rev., 1992,92:965-994

    5. [5] Möhring P C, Coville N J. J. Organomet. Chem., 1994,479:1-29[5] Möhring P C, Coville N J. J. Organomet. Chem., 1994,479:1-29

    6. [6] Brintzinger H H, Fischer D, Mülhaupt R, et al. Angew. Chem., Int. Ed. Engl., 1995,34:1143-1170[6] Brintzinger H H, Fischer D, Mülhaupt R, et al. Angew. Chem., Int. Ed. Engl., 1995,34:1143-1170

    7. [7] Resconi L, Cavallo L, Fait A, et al. Chem. Rev., 2000,100: 1253-1345[7] Resconi L, Cavallo L, Fait A, et al. Chem. Rev., 2000,100: 1253-1345

    8. [8] Frankcom T M, Green J C, Nagy A, et al. Organometallics, 1993,12:3688-3697[8] Frankcom T M, Green J C, Nagy A, et al. Organometallics, 1993,12:3688-3697

    9. [9] Bonifaci C, Ceccon A, Santi S, et al. Inorg. Chim. Acta, 1995, 240:541-549[9] Bonifaci C, Ceccon A, Santi S, et al. Inorg. Chim. Acta, 1995, 240:541-549

    10. [10] Gamasa M P, Gimeno J, Gonzalez-bernardo C, et al. Organ-ometallics, 1996,15:302-308[10] Gamasa M P, Gimeno J, Gonzalez-bernardo C, et al. Organ-ometallics, 1996,15:302-308

    11. [11] MA Zhi-Hong(马志宏), LI Fang(李放), LIU Xiao-Huan(刘 晓焕), et al. Chinese J. Org. Chem.(有机化学), 2009,29: 1294-1297[11] MA Zhi-Hong(马志宏), LI Fang(李放), LIU Xiao-Huan(刘 晓焕), et al. Chinese J. Org. Chem.(有机化学), 2009,29: 1294-1297

    12. [12] GUO Kai-Ming(郭凯明), MA Zhi-Hong(马志宏), LI Su-Zhen (李素贞), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:643-646[12] GUO Kai-Ming(郭凯明), MA Zhi-Hong(马志宏), LI Su-Zhen (李素贞), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:643-646

    13. [13] Ma Z, Fan D, Li S, et al. New. J. Chem., 2015,39:1075-1082[13] Ma Z, Fan D, Li S, et al. New. J. Chem., 2015,39:1075-1082

    14. [14] Coates G W, Waymouth R M. Science, 1995,267:217-219[14] Coates G W, Waymouth R M. Science, 1995,267:217-219

    15. [15] Bruce M D, Coates G W, Hauptman E, et al. J. Am. Chem. Soc., 1997,119:11174-11182[15] Bruce M D, Coates G W, Hauptman E, et al. J. Am. Chem. Soc., 1997,119:11174-11182

    16. [16] Kravchenko R, Masood A, Waymouth R M, et al. J. Am. Chem. Soc., 1998,120:2039-2046[16] Kravchenko R, Masood A, Waymouth R M, et al. J. Am. Chem. Soc., 1998,120:2039-2046

    17. [17] Zhang F, Mu Y, Zhao L, et al. J. Organomet. Chem., 2000, 613:68-76[17] Zhang F, Mu Y, Zhao L, et al. J. Organomet. Chem., 2000, 613:68-76

    18. [18] Zhang F, Mu Y, Wang J, et al. Polyhedron, 2000,19:1941-1947[18] Zhang F, Mu Y, Wang J, et al. Polyhedron, 2000,19:1941-1947

    19. [19] Grimmer N E, Coville N J, de Koning C B, et al. J. Organo-met. Chem., 2000,616:112-127[19] Grimmer N E, Coville N J, de Koning C B, et al. J. Organo-met. Chem., 2000,616:112-127

    20. [20] Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[20] Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    21. [21] Chen D F, Xu S S, Song H B, et al. Eur. J. Inorg. Chem., 2008:1854-1864[21] Chen D F, Xu S S, Song H B, et al. Eur. J. Inorg. Chem., 2008:1854-1864

    22. [22] Sridevi V S, Leong W K. J. Organomet. Chem., 2007,692: 4909-4916[22] Sridevi V S, Leong W K. J. Organomet. Chem., 2007,692: 4909-4916

    23. [23] Liu X H, Ma Z H, Tian L J, et al. Transition Met. Chem., 2010,35:393-397[23] Liu X H, Ma Z H, Tian L J, et al. Transition Met. Chem., 2010,35:393-397

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  179
  • HTML全文浏览量:  33
文章相关
  • 收稿日期:  2015-01-09
  • 网络出版日期:  2015-02-06
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net