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三维Mn(Ⅱ)-Sm(Ⅱ)杂核和二维同核Sm(Ⅱ)配合物的合成、晶体结构与性质

陈满生 ,  邓奕芳 ,  崔莺 ,  刘冬成 ,  梁福沛

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引用本文: 陈满生, 邓奕芳, 崔莺, 刘冬成, 梁福沛. 三维Mn(Ⅱ)-Sm(Ⅱ)杂核和二维同核Sm(Ⅱ)配合物的合成、晶体结构与性质[J]. 无机化学学报, 2015, (5): 1041-1048. doi: 10.11862/CJIC.2015.130 shu
Citation:  CHEN Man-Sheng, DENG Yi-Fang, CUI Ying, LIU Dong-Cheng, LIANG Fu-Pei. Syntheses, Crystal Structures and Properties of 3D Heteronuclear Mn(Ⅱ)-Sm(Ⅱ) and 2D Homonuclear Sm(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 1041-1048. doi: 10.11862/CJIC.2015.130 shu

三维Mn(Ⅱ)-Sm(Ⅱ)杂核和二维同核Sm(Ⅱ)配合物的合成、晶体结构与性质

  • 1.

    1 广西师范大学化学与药学学院, 桂林 541004;

  • 2.

    2 衡阳师范学院化学与材料科学系, 功能金属有机材料湖南省普通高等学校重点实验室, 衡阳 421008

    • 通讯作者: 陈满生 cmsniu@163.com, 梁福沛 liangfupei@glut.edu.cn; 陈满生 cmsniu@163.com, 梁福沛 liangfupei@glut.edu.cn
  • 基金项目:

    国家自然科学基金(No.21461004,21271050) (No.21461004,21271050)

    中国博士后科学基金(No.2014M552534XB) (No.2014M552534XB)

    湖南省教育厅重点项目(No.14A021) (No.14A021)

    福建省教育厅A类重点(No.JA14261) (No.JA14261)

    功能金属有机材料湖南省普通高等学校重点实验室项目(No.13K06)资助和湖南省重点学科建设项目资助。 (No.13K06)

摘要: 利用过渡金属锰盐与稀土盐水热合成了杂核化合物{[MnSm2(INAIP)4(H2O)4]·2H2O}n(1)和同核{[Sm(INAIP)(HINAIP)]·2H2O}n(2)(INAIP=异烟酰胺吡啶基异酞酸根),并对其进行了元素分析、IR及X-射线衍射法表征。晶体结构研究表明:配合物1属于三斜晶系,P1空间群。晶胞参数:a=1.0188(5)nm,b=1.08386(6)nm,c=1.38721(8)nm,V=1.475(14)nm3,Z=1,Dc=1.802g·cm-3,μ=2.271mm-1,F(000)=793,Rint=0.0105,R1=0.0512,wR2=0.1319。配合物2属于单斜晶系,P21/c空间群。晶胞参数:a=1.34305(18)nm,b=1.3765(17)nm,c=1.62408(15)nm,V=2.7028(6)nm3,Z=4,Dc=1.861g·cm-3,μ=2.251mm-1,F(000)=1500,Rint=0.0514,R1=0.0322,wR2=0.0887。配合物1是由配体INAIP连接稀土钐离子形成二维层状结构,该二维层通过Mn-O和Mn-N键连接成三维非贯穿网络结构。而配合物2是由配体INAIP连接稀土钐离子形成二维双层状结构,该二维层通过氢键连接成三维网络结构。配合物1失去水分子后具有稳定微孔结构,对二氧化碳具有一定的吸附,而对氮气没有吸附作用。此外,配合物1和2具有典型的稀土钐离子红色荧光性能。

English

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  • 收稿日期:  2014-12-24
  • 网络出版日期:  2015-01-30
通讯作者: 陈斌, bchen63@163.com
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