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苯基-吡唑铜(Ⅱ)和钴(Ⅱ)配合物的合成、结构及其仿生催化溴化活性

王继虓 ,  王澈 ,  高雪 ,  王志楠 ,  张小溪 ,  冯晓东 ,  韦思跃 ,  邢永恒 ,  施展

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引用本文: 王继虓, 王澈, 高雪, 王志楠, 张小溪, 冯晓东, 韦思跃, 邢永恒, 施展. 苯基-吡唑铜(Ⅱ)和钴(Ⅱ)配合物的合成、结构及其仿生催化溴化活性[J]. 无机化学学报, 2015, (5): 923-929. doi: 10.11862/CJIC.2015.122 shu
Citation:  WANG Ji-Xiao, WANG Che, GAO Xue, WANG Zhi-Nan, ZHANG Xiao-Xi, FENG Xiao-Dong, WEI Si-Yue, XING Yong-Heng, SHI Zhan. Copper(Ⅱ) and Cobalt(Ⅱ) Complexes with Arene-Linked Pyrazolyl Methane: Syntheses, Structures and Mimicking Catalytic Activity in Brominating Reaction[J]. Chinese Journal of Inorganic Chemistry, 2015, (5): 923-929. doi: 10.11862/CJIC.2015.122 shu

苯基-吡唑铜(Ⅱ)和钴(Ⅱ)配合物的合成、结构及其仿生催化溴化活性

  • 1.

    1 辽宁师范大学化学化工学院, 大连 116029;

  • 2.

    2 吉林大学化学学院无机合成与制备化学国家重点实验室, 长春 130012

    • 通讯作者: 邢永恒 xingyongheng2000@163.com, 王澈 wangche126@126.com; 邢永恒 xingyongheng2000@163.com, 王澈 wangche126@126.com
  • 基金项目:

    国家自然科学基金(No.21071071、21371086) (No.21071071、21371086)

    辽宁省科学事业公益基金(No.2014003019) (No.2014003019)

    无机合成与制备化学国家重点实验室(吉林大学)开放课题基金(No.2013-05)资助项目。 (吉林大学)开放课题基金(No.2013-05)

摘要: 在无水乙醇体系中设计合成了2种配合物:[Cu(L1)Cl2]·0.5C2H5OH(1)和Co(L1)Cl2(2)(L1=1,4-双(吡唑甲基)苯)。通过元素分析、红外光谱、热重、X-射线粉末和X-射线单晶衍射方法对其结构进行了表征,分析了其光谱及结构特征。结构分析表明,配合物1中金属配位数为5,形成四角锥构型,配合物2的中心金属配位数为4,形成了扭曲四面体构型,配体1,4-双(吡唑甲基)苯采取二齿桥联配位模式。通过仿生催化溴化动力学研究,发现上述配合物均表现出潜在的催化溴化活性。

English

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  • 收稿日期:  2014-11-17
  • 网络出版日期:  2015-01-28
通讯作者: 陈斌, bchen63@163.com
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