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类水滑石Ti/Li/Al-LDHs的制备及其CO2吸附性能

孔婷婷 ,  董羿蘩 ,  张颖萍 ,  张亚刚 ,  周安宁

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引用本文: 孔婷婷, 董羿蘩, 张颖萍, 张亚刚, 周安宁. 类水滑石Ti/Li/Al-LDHs的制备及其CO2吸附性能[J]. 燃料化学学报, 2016, 44(08): 1017-1024. shu
Citation:  KONG Ting-ting, DONG Yi-fan, ZHANG Ying-ping, ZHANG Ya-gang, ZHOU An-ning. Preparation of hydrotalcite-like Ti/Li/Al-LDHs and its performance in CO2 adsorption[J]. Journal of Fuel Chemistry and Technology, 2016, 44(08): 1017-1024. shu

类水滑石Ti/Li/Al-LDHs的制备及其CO2吸附性能

  • 1.

    西安科技大学 化学与化工学院, 陕西 西安 710054

    • 通讯作者: 周安宁
  • 基金项目:

    国家自然科学基金（51074122）资助 

摘要: 采用共沉淀法制备了一系列新型的类水滑石Ti/Li/Al-LDHs材料，通过原子吸收光谱（AAS）、X射线衍射（XRD）、扫描电镜（SEM）、热重分析（TG）和傅里叶变换红外光谱（FT-IR）等技术对其进行了表征，研究了不同金属元素比例和焙烧温度对该Ti/Li/Al-LDHs材料的结构、形貌及其CO2吸附性能的影响。结果表明，当Ti/Li/Al比为1：3：4时，水滑石Ti/Li/Al-LDHs的结晶度最好，形貌最规整，而Ti/Li/Al比为1：3：2、300℃下焙烧后得到的Ti1Li3Al2-LDHs300的CO2吸附性能最好。Ti1Li3Al2-LDHs300上CO2吸附量可达53.5mg/g，10次循环吸附后，CO2吸附量仅下降了2.4%。

English

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  • 收稿日期:  2016-04-07
  • 网络出版日期:  2016-06-18
通讯作者: 陈斌, bchen63@163.com
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