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Ni-Fe/蒙脱土催化剂催化乙醇水蒸气重整制氢的研究

李宝茹 ,  殷雪梅 ,  吴旭 ,  安霞 ,  谢鲜梅

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引用本文: 李宝茹, 殷雪梅, 吴旭, 安霞, 谢鲜梅. Ni-Fe/蒙脱土催化剂催化乙醇水蒸气重整制氢的研究[J]. 燃料化学学报, 2016, 44(08): 993-1000. shu
Citation:  LI Bao-ru, YIN Xue-mei, WU Xu, AN Xia, XIE Xian-mei. Montmorillonite supported Ni-Fe catalysts for hydrogen production from steam reforming of ethanol[J]. Journal of Fuel Chemistry and Technology, 2016, 44(08): 993-1000. shu

Ni-Fe/蒙脱土催化剂催化乙醇水蒸气重整制氢的研究

  • 1.

    太原理工大学 化学化工学院, 山西 太原 030024

    • 通讯作者: 谢鲜梅
  • 基金项目:

    国家自然科学基金（51541210) 

    山西省自然科学基金（2013021008-4）资助 

摘要: 采用浸渍法制备了一系列Ni-Fe/蒙脱土（MMT）催化剂，并应用于乙醇水蒸气重整制氢反应（ESR）。采用X射线衍射（XRD）、N2吸附脱附分析和H2-程序升温还原（H2-TPR）表征手段对催化剂的物理化学性质、还原性能、碳沉积等进行了研究。结果表明，Ni-Fe/MMT催化剂中，Ni、Fe高度分散在载体MMT层间及表面，而且Fe的加入降低了Ni颗粒的粒径，增强了Ni2+与载体的相互作用力。以10Ni5Fe/MMT为催化剂，在反应温度为500℃、水醇比为3：1、空速为12h-1，反应进行30h后，乙醇转化率为100%，氢气选择性仍保持72%，副产物CO和CH4含量明显降低。这是因为催化助剂Fe的引入，一方面，提高了Ni的分散度，使得ESR低温活性较好；另一方面，减小了Ni颗粒粒径，小颗粒的Ni有利于抑制甲烷的生成，并且Fe的加入加强了甲烷重整和水煤气变换反应，提高产物中氢气的选择性。

English

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  • 收稿日期:  2016-02-04
  • 网络出版日期:  2016-05-12
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