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两种N-2-嘧啶基-4-氨基苯磺酰Co(Ⅱ)配合物的合成、晶体结构及电催化性能研究

冉繁敏 ,  赵亚云 ,  赵秀华 ,  张洁 ,  潘建国 ,  李星

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引用本文: 冉繁敏, 赵亚云, 赵秀华, 张洁, 潘建国, 李星. 两种N-2-嘧啶基-4-氨基苯磺酰Co(Ⅱ)配合物的合成、晶体结构及电催化性能研究[J]. 无机化学学报, 2014, 30(4): 913-920. doi: 10.11862/CJIC.2014.092 shu
Citation:  RAN Fan-Min, ZHAO Ya-Yun, ZHAO Xiu-Hua, ZHANG Jie, PAN Jian-Guo, LI Xing. Syntheses, Crystal Structures and Electrochemical Behaviors of Two Co(Ⅱ) Complexes with N-2-Pyrimidinyl-4-amino-benzenesulfonamides[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 913-920. doi: 10.11862/CJIC.2014.092 shu

两种N-2-嘧啶基-4-氨基苯磺酰Co(Ⅱ)配合物的合成、晶体结构及电催化性能研究

    通讯作者: 李星 lixing@nbu.edu.cn,lix905@126.com
  • 基金项目:

    国家自然科学基金(No.20971075,61078055)；结构化学国家重点实验室基金(No.20110010)；浙江省自然科学基金(No.LY12B01005)；宁波大学王宽诚幸福基金资助项目。 (No.20971075,61078055)；结构化学国家重点实验室基金(No.20110010)；浙江省自然科学基金(No.LY12B01005)

摘要: 水热法合成两种新的Co(Ⅱ)化合物[Co(SD)2(2,2’-bpy)](1)和{[Co(SD)2(4,4’-bpy)]·4H2O}n(2)(SD=N-2-嘧啶基-4-氨基苯磺酰,2,2’-bpy=2,2’-联吡啶,4,4’-bpy=4,4’-联吡啶),并通过元素分析、红外光谱、X射线粉末衍射、热重分析、循环伏安法进行结构和性能表征。单晶X-ray衍射分析表明化合物1是三斜晶系,空间群为P1；化合物2是单斜晶系,空间群为C2/c。电催化实验发现化合物1和2对H2O2、HCHO都具有良好的电催化活性。

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  • 收稿日期:  2013-07-30
  • 网络出版日期:  2013-10-26
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