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以3, 5-二甲基-1H-1, 2, 4-三氮唑及对苯二甲酸根构筑的三维锌配位聚合物的合成、晶体结构及荧光性质

黄遥 ,  周明善 ,  朱超 ,  刘龙江 ,  周晓俊 ,  张永明 ,  付飞娥 ,  金娥

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引用本文: 黄遥, 周明善, 朱超, 刘龙江, 周晓俊, 张永明, 付飞娥, 金娥. 以3, 5-二甲基-1H-1, 2, 4-三氮唑及对苯二甲酸根构筑的三维锌配位聚合物的合成、晶体结构及荧光性质[J]. 无机化学学报, 2014, 30(4): 901-906. doi: 10.11862/CJIC.2014.045 shu
Citation:  HUANG Yao, ZHOU Ming-Shan, ZHU Chao, LIU Long-Jiang, ZHOU Xiao-Jun, ZHANG Yong-Ming, FU Fei-E, JIN E. Synthesis, Structures and Luminescence Property of a 3D Zinc Coordination Polymer Based on 3, 5-Dimethyl-1H-1, 2, 4-triazole and 1,4-Benzenedicarboxylate Dianion[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 901-906. doi: 10.11862/CJIC.2014.045 shu

以3, 5-二甲基-1H-1, 2, 4-三氮唑及对苯二甲酸根构筑的三维锌配位聚合物的合成、晶体结构及荧光性质

    通讯作者: 黄遥 ynou_hy@163.com
  • 基金项目:

    云南科技厅应用基础研究计划面上项目(No.2011FZ198)；云南教育厅科研基金重点项目(No.2011Z009)资助项目。 (No.2011FZ198)；云南教育厅科研基金重点项目(No.2011Z009)

摘要: 水热法合成了1个新颖的锌配位聚合物{[Zn3(Hdmtrz)2(1,4-bdc)3]·2H2O}n(1,Hdmtrz=3,5-二甲基-1-H-1,2,4-三氮唑,1,4-bdc=对苯二甲酸根),对其进行了红外光谱、元素分析、X射线粉末衍射和热重分析等表征,并用X-射线单晶衍射法测定了配合物的单晶结构。该配合物属三斜晶系,P1空间群,晶胞参数为a=0.91797(18)nm,b=0.9833(2)nm,c=1.0717(2)nm,α=100.81(3)°,β=102.589(3)°,γ=106.90(3)°,V=0.8418(3)nm3,Z=1。该化合物为三维框架结构,拓扑类型为pcuα-Po简单立方格子,Schläfli符号记为{412·63}。室温固态荧光测试显示,配合物在471nm(λmax)具有强的荧光吸收。

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  • 收稿日期:  2013-05-20
  • 网络出版日期:  2013-09-18
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