氢氧化物盐插层材料的制备和表征

引用本文: 刘洁翔, 张永清, 张晓光, 王建龙, 赵凌峰, 杨津, 王瑞. 氢氧化物盐插层材料的制备和表征[J]. 无机化学学报, 2014, 30(4): 837-844. doi: 10.11862/CJIC.2014.129 shu

Citation: LIU Jie-Xiang, ZHANG Yong-Qing, ZHANG Xiao-Guang, WANG Jian-Long, ZHAO Ling-Feng, YANG Jin, WANG Rui. Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)[J]. Chinese Journal of Inorganic Chemistry, 2014, 30(4): 837-844. doi: 10.11862/CJIC.2014.129 shu

氢氧化物盐插层材料的制备和表征

刘洁翔 ^{1,
,} ,
张永清 ^1, ,
张晓光 ^{2,
,} ,
王建龙 ^1, ,
赵凌峰 ^1, ,
杨津 ^1, ,
王瑞 ^1,

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

基金项目:
河北省自然科学基金(No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050) (No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050)

“大学生创新创业训练计划”国家级项目(No.201310080018)资助项目。 (No.201310080018)

摘要: 以层状氢氧化锌硝酸盐(Zn-LHS)和氢氧化镍锌硝酸盐(NiZn-LHS)为主体,采用共沉淀和离子交换法制备十二烷基苯磺酸根离子(DBS)和磺丁基醚-β-环糊精(SBE-β-CD)插层氢氧化物盐(Zn-LHS-DBS和NiZn-LHS-SBE-β-CD),系统考察客体阴离子浓度和pH值等因素对插层材料超分子结构的影响,并用XRD、FT-IR、TG-DTA和SEM对其结构、热稳定性和形貌等进行表征。结果表明,采用共沉淀法在DBS浓度为0.19~0.38mol·L^-1,pH=6.0~7.0,水热温度60~100℃条件下合成晶型单一且结构完整Zn-LHS-DBS；采用离子交换法可合成结构完整NiZn-LHS-SBE-β-CD；无论离子交换还是共沉淀法都不能合成单一晶型Zn-LHS-SBE-β-CD,这可能与SBE-β-CD分子结构以及Zn-LHS水热稳定性差有关。此外,由于氢氧化物盐层板和客体间存在超分子作用而导致DBS和SBE-β-CD在层间具有较高热稳定性。

关键词:

氢氧化锌硝酸盐;氢氧化镍锌硝酸盐;十二烷基苯磺酸钠;磺丁基醚-β-环糊精;热稳定性

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

Received Date: 15 September 2013
Fund Project:
河北省自然科学基金(No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050)

“大学生创新创业训练计划”国家级项目(No.201310080018)资助项目。

Abstract: Intercalation of dodecyl benzene sulphonate (DBS) and sulfobutyl ether β-cyclodextrin (SBE-β-CD) into layered zinc hydroxide nitrate (Zn-LHS) and nickel/zinc hydroxide nitrate (NiZn-LHS) was synthesized by coprecipitation and ion-exchanged methods. The effect of anion concentration and pHvalue on preparation was systematically investigated and compared. The products were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetry and differential thermal analysis (TG-DTA), and scanning electron microscope (SEM). The results showed that Zn-LHS-DBS with pure phase and good crystallinity was obtained at DBS concentration of 0.19~0.38 mol·L^-1, pH=6.0~7.0, temperature of hydrothermal treatment of 60~100 ℃ by coprecipitation method. The NiZn-LHS-SBE-β-CD with good structure was prepared by ion-exchanged method. Zn-LHS-SBE-β-CD with pure phase was not successfully prepared by both coprecipitation and ion-exchanged method due to the particular structure of SBE-β-CD and poor hydrothermal stability of Zn-LHS. Furthermore, TG-DTA data indicated that stability of SBE-β-CD and DBSimproved distinctly in the interlayer due to the strong supra-molecular interaction existed between anions and hostlayer of LHS.

Key words:

zinc hydroxide nitrate;nickel/zinc hydroxide nitrate;dodecyl benzene sulphonate;sulfobutyl ether β-cyclodextrin;thermostability

1. [1] Arízaga G G C. J. Solid State Chem., 2012, 185:150-155[1] Arízaga G G C. J. Solid State Chem., 2012, 185:150-155
2. [2] Demel J, Kubát P, Jirka I, et al. J. Phys. Chem. C, 2010, 114:16321-16328[2] Demel J, Kubát P, Jirka I, et al. J. Phys. Chem. C, 2010, 114:16321-16328
3. [3] Rojas R, Giacomelli C E. Colloid Surf. A, 2013, 419:166-173[3] Rojas R, Giacomelli C E. Colloid Surf. A, 2013, 419:166-173
4. [4] Yang J H, Han Y S, Park M, et al. Chem. Mater., 2007, 19: 2679-2685[4] Yang J H, Han Y S, Park M, et al. Chem. Mater., 2007, 19: 2679-2685
5. [5] Biswick T D, Park H, Shul Y G, et al. J. Phys. Chem. Solids, 2010, 71:647-649[5] Biswick T D, Park H, Shul Y G, et al. J. Phys. Chem. Solids, 2010, 71:647-649
6. [6] Biswick T, Park D H, Choy J H. J. Phys. Chem. Solids, 2012, 73:1510-1513[6] Biswick T, Park D H, Choy J H. J. Phys. Chem. Solids, 2012, 73:1510-1513
7. [7] Bull R M R, Markland C, Williams G R, et al. J. Mater. Chem., 2011, 21:1822-1828[7] Bull R M R, Markland C, Williams G R, et al. J. Mater. Chem., 2011, 21:1822-1828
8. [8] Hussein M Z, Hashim N, Yahaya A H, et al. Solid State Sci., 2010, 12:770-775[8] Hussein M Z, Hashim N, Yahaya A H, et al. Solid State Sci., 2010, 12:770-775
9. [9] Wang B, Zhang H, Evans David G, et al. Mater. Chem. Phys., 2005, 92:190-196[9] Wang B, Zhang H, Evans David G, et al. Mater. Chem. Phys., 2005, 92:190-196
10. [10] Liu X L, Wei M, Wang Z L, et al. J. Phys. Chem. C, 2008, 112:17517-17524[10] Liu X L, Wei M, Wang Z L, et al. J. Phys. Chem. C, 2008, 112:17517-17524
11. [11] Nakayama H, Kuwano K, Tsuhako M. J. Phys. Chem. Solids, 2008, 69:1552-1555[11] Nakayama H, Kuwano K, Tsuhako M. J. Phys. Chem. Solids, 2008, 69:1552-1555
12. [12] Rajamathi J T, Ravishankar N, Rajamathi M. Solid State Sci., 2005, 7:195-199[12] Rajamathi J T, Ravishankar N, Rajamathi M. Solid State Sci., 2005, 7:195-199
13. [13] bin Hussein M Z, Ghotbi M Y, Yahaya A H, et al. Solid State Sci., 2009, 11:368-375[13] bin Hussein M Z, Ghotbi M Y, Yahaya A H, et al. Solid State Sci., 2009, 11:368-375
14. [14] Marangoni R, Ramos L P, Wypych F. J. Colloid Interface Sci., 2009, 330:303-309[14] Marangoni R, Ramos L P, Wypych F. J. Colloid Interface Sci., 2009, 330:303-309
15. [15] XING Fang-Fang(邢方方), NI Zhe-Ming(倪哲明), WANG Ping(王平), et al. Acta Chim. Sin.(化学学报), 2007, 65(23): 2738-2742[15] XING Fang-Fang(邢方方), NI Zhe-Ming(倪哲明), WANG Ping(王平), et al. Acta Chim. Sin.(化学学报), 2007, 65(23): 2738-2742
16. [16] Newman S P, Jones W C. J. Solid State Chem., 1999, 148: 26-40[16] Newman S P, Jones W C. J. Solid State Chem., 1999, 148: 26-40
17. [17] Quan Z L, Yang H, Zheng B, et al. Colloid Surf. A, 2009, 348:164-169[17] Quan Z L, Yang H, Zheng B, et al. Colloid Surf. A, 2009, 348:164-169
18. [18] Rojas R, Ángeles Ulibarri M, Barriga C, et al. Appl. Clay Sci., 2010, 49:176-181[18] Rojas R, Ángeles Ulibarri M, Barriga C, et al. Appl. Clay Sci., 2010, 49:176-181
19. [19] del Arco M, Gutiérrez S, Martín C, et al. J. Solid State Chem., 2004, 177:3954-3962[19] del Arco M, Gutiérrez S, Martín C, et al. J. Solid State Chem., 2004, 177:3954-3962
20. [20] Wang J, Wei M, Rao G Y, et al. Solid State Chem., 2004, 177:366-371[20] Wang J, Wei M, Rao G Y, et al. Solid State Chem., 2004, 177:366-371
21. [21] Cursino A C T, Gardolinski da Costa Gardolinski J E F. J. Colloid Interface Sci., 2010, 347:49-55[21] Cursino A C T, Gardolinski da Costa Gardolinski J E F. J. Colloid Interface Sci., 2010, 347:49-55
22. [22] MacPhail R A, Strauss H L, Snyder R G, et al. J. Phys. Chem., 1984, 88:334-341[22] MacPhail R A, Strauss H L, Snyder R G, et al. J. Phys. Chem., 1984, 88:334-341
23. [23] Moujhaid E M, Inacio J, Besse J P, et al. Micro. Meso. Mater., 2003, 57:37-46[23] Moujhaid E M, Inacio J, Besse J P, et al. Micro. Meso. Mater., 2003, 57:37-46
24. [24] Pérez-Ramírez J, Mul G, Kapteijn F, et al. J. Mater. Chem., 2001, 11:821-830[24] Pérez-Ramírez J, Mul G, Kapteijn F, et al. J. Mater. Chem., 2001, 11:821-830
25. [25] Wypych F, Arízaga G G C, da Costa Gardolinski J E F. J. Colloid Interface Sci., 2005, 283:130-138[25] Wypych F, Arízaga G G C, da Costa Gardolinski J E F. J. Colloid Interface Sci., 2005, 283:130-138
26. [26] WANG Bin(王斌). Thesis for the Master's Degree of Beijing University of Chemical Technology(北京化工大学硕士毕业论文), 2005.[26] WANG Bin(王斌). Thesis for the Master's Degree of Beijing University of Chemical Technology(北京化工大学硕士毕业论文), 2005.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 1251
HTML全文浏览量: 100

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

氢氧化物盐插层材料的制备和表征

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

氢氧化物盐插层材料的制备和表征

通讯作者: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

English

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

Corresponding author: 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn; 刘洁翔 jxliu@hebut.edu.cn,张晓光 xgzhang@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs