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减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化

李美惠 ,  马文超 ,  毕亚东 ,  陈冠益 ,  陈慧

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引用本文: 李美惠, 马文超, 毕亚东, 陈冠益, 陈慧. 减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化[J]. 燃料化学学报, 2015, 43(3): 309-314. shu
Citation:  LI Mei-hui, MA Wen-chao, BI Ya-dong, CHEN Guan-yi, CHEN Hui. Catalytic co-cracking of reduced pressure distillation of bio-oil and ethanol over ZSM-5/MCM-41[J]. Journal of Fuel Chemistry and Technology, 2015, 43(3): 309-314. shu

减压蒸馏生物油与乙醇在ZSM-5/MCM-41上共催化裂化

    通讯作者: 马文超,博士,Tel:18602272358,E-mail:mawc916@tju.edu.cn。
  • 基金项目:

    国家自然科学基金(51036006, 51306131)。 (51036006, 51306131)

摘要: 采用减压蒸馏生物油为原料,与无水乙醇2:3(质量比)混合,在固定床中ZSM-5/MCM-41分子筛上共催化裂化,考查了反应温度和质量空速(WHSV)对裂化产物的影响。对ZSM-5/MCM-41进行了NH3-TPD、BET、N2吸附-脱附等表征,对裂化气体产物通过气相色谱仪分析,减压蒸馏生物油和精制生物油采用气相色谱-质谱联用仪进行定量分析。结果表明,反应温度500 ℃、WHSV 3.75 h-1为反应优化工况。此反应条件下,精制生物油酸类物质从减压蒸馏生物油中的25.6%降至反应后的0.1%,效果显著,且精制生物油产率为46.8%,气体产物中CO2和CO的浓度共9.5%。

English

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