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Ni/Al2O3改性催化剂催化重整生物油模拟物制氢研究

谢登印 ,  张素平 ,  陈志远 ,  陈振奇 ,  许庆利

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引用本文: 谢登印, 张素平, 陈志远, 陈振奇, 许庆利. Ni/Al2O3改性催化剂催化重整生物油模拟物制氢研究[J]. 燃料化学学报, 2015, 43(3): 302-308. shu
Citation:  XIE Deng-yin, ZHANG Su-ping, CHEN Zhi-yuan, CHEN Zhen-qi, XU Qing-li. Co and Cu modified Ni/Al2O3 steam reforming catalysts for hydrogen production from model bio-oil[J]. Journal of Fuel Chemistry and Technology, 2015, 43(3): 302-308. shu

Ni/Al2O3改性催化剂催化重整生物油模拟物制氢研究

    通讯作者: 张素平,Tel:021-64253283,E-mail:zsp@ecust.edu.cn。
  • 基金项目:

    国家支撑计划(2014BAD02B03) (2014BAD02B03)

    国家自然科学基金(51176049) (51176049)

    教育部新世纪优秀人才支持计划(NCET-11-0642)。 (NCET-11-0642)

摘要: 制备了Ni/Al2O3、Ni-Cu/Al2O3、Ni-Co/Al2O3和Ni-Co-Cu/Al2O3催化剂,研究了Co和Cu对生物油水蒸气催化重整的影响。实验表明,Co 能促进水汽变换(WGS)反应,提高氢气的产率,Cu能抑制反应中焦炭的形成,提高催化剂的稳定性。对催化剂Ni-Co-Cu/Al2O3进行工艺条件考察,当900 ℃、水油比为6 g/g、质量空速(WHSV)为1 h-1时,碳选择性达到87.5%,氢气产率达到84.2%,潜在氢气产率达到92.4%。

English

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  • 收稿日期:  2014-09-24
通讯作者: 陈斌, bchen63@163.com
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