注册 English

CuCrO2的合成及其复合催化剂的光催化性能

刘宗园 ,  王桂赟 ,  刘先平 ,  王延吉

downloadPDF
引用本文: 刘宗园, 王桂赟, 刘先平, 王延吉. CuCrO2的合成及其复合催化剂的光催化性能[J]. 燃料化学学报, 2013, 41(12): 1473-1480. shu
Citation:  LIU Zong-yuan, WANG Gui-yun, LIU Xian-ping, WANG Yan-ji. Preparation of CuCrO2 and the photocatalytic properties of its composites[J]. Journal of Fuel Chemistry and Technology, 2013, 41(12): 1473-1480. shu

CuCrO2的合成及其复合催化剂的光催化性能

    通讯作者: 王桂赟，Tel：022-60202489，E-mail：wgy1964@hebut.edu.cn。
  • 基金项目:

    国家自然科学基金（21076058）；河北省重大技术创新项目（12275603Z）。 

摘要: 以硝酸铬和硝酸铜为原料，通过半湿法经两种不同路径合成了CuCrO2半导体物质。分别采用热重-差示扫描（TG-DSC）、X射线衍射（XRD）、紫外-可见漫反射（UV-vis DR）、扫描电镜（SEM）及X射线光电子能谱（XPS）对样品进行了表征分析。确立了以氨水为Cr3+沉淀剂制得的氢氧化铬沉淀中加入硝酸铜溶液是合成CuCrO2较适宜的路径。借助TG-DSC和XRD的分析结果确立前驱体在热处理的过程中，含Cr物相的变化历程为Cr（OH）3 → CuCrO4 → CuCr2O4 → CuCrO2。通过机械研磨的方法合成了CuCrO2-WO3和CuCrO2-ZnO复合型催化剂，对其进行了XRD、SEM和XPS表征分析，并测试了复合催化剂的光催化活性。结果表明，与单独使用CuCrO2相比，无论是以高压汞灯，还是以氙灯为光源，CuCrO2-WO3和CuCrO2-ZnO的光催化产氢活性都有显著提高。

English

  • 

    1. [1] LIU Z Y, BAI H W, XU S P, SUN D D. Hierarchical CuO/ZnO "corn-like" architecture for photocatalytic hydrogen generation[J]. Int J Hydrogen Energy, 2011, 36(21): 13473-13480.[1] LIU Z Y, BAI H W, XU S P, SUN D D. Hierarchical CuO/ZnO "corn-like" architecture for photocatalytic hydrogen generation[J]. Int J Hydrogen Energy, 2011, 36(21): 13473-13480.

    2. [2] QIN Y, WANG G Y, WANG Y J. Study on the photacatalytic property of La-doped CoO/SrTiO3[J]. Catal Commun, 2007, 8(6): 926-930.[2] QIN Y, WANG G Y, WANG Y J. Study on the photacatalytic property of La-doped CoO/SrTiO3[J]. Catal Commun, 2007, 8(6): 926-930.

    3. [3] LIN H Y, CHEN Y F, CHEN Y W. Water splitting reaction on NiO/InVO4 under visible light irradiation[J]. Int J Hydrogen Energy, 2007, 32(1): 86-92.[3] LIN H Y, CHEN Y F, CHEN Y W. Water splitting reaction on NiO/InVO4 under visible light irradiation[J]. Int J Hydrogen Energy, 2007, 32(1): 86-92.

    4. [4] KAKUTA S, ABE T. Structural characterization of Cu2O after the evolution of H2 under visible light irradiation[J]. Electrochem Solid-State Lett, 2009, 12(3): 1-3.[4] KAKUTA S, ABE T. Structural characterization of Cu2O after the evolution of H2 under visible light irradiation[J]. Electrochem Solid-State Lett, 2009, 12(3): 1-3.

    5. [5] ZHOU S, FANG X D, DENG Z H, LI D, DONG W W, TANO R H, MENG G, WANG T, ZHU X B. Hydrothermal synthesis and characterization of CuCrO2 laminar nanocrystals[J]. J Cryst Growth, 2008, 310(24): 5375-5379.[5] ZHOU S, FANG X D, DENG Z H, LI D, DONG W W, TANO R H, MENG G, WANG T, ZHU X B. Hydrothermal synthesis and characterization of CuCrO2 laminar nanocrystals[J]. J Cryst Growth, 2008, 310(24): 5375-5379.

    6. [6] SAADI S, BOUGUELIA A, TRARI M. Photocatalytic hydrogen evolution over CuCrO2[J]. Sol Energy, 2006, 80(3): 272-280.[6] SAADI S, BOUGUELIA A, TRARI M. Photocatalytic hydrogen evolution over CuCrO2[J]. Sol Energy, 2006, 80(3): 272-280.

    7. [7] KETIR W, BOUGUELIA A, TRARI M. NO3- removal with a new delafossite CuCrO2 photocatalyst[J]. Desalination, 2009, 244(1): 144-152.[7] KETIR W, BOUGUELIA A, TRARI M. NO3- removal with a new delafossite CuCrO2 photocatalyst[J]. Desalination, 2009, 244(1): 144-152.

    8. [8] BELHADI A, BOUMAZA S, TRARI M. Photoassisted hydrogen production under visible light over NiO/ZnO hetero-system[J]. Appl Energy, 2011, 88(12): 4490-4495.[8] BELHADI A, BOUMAZA S, TRARI M. Photoassisted hydrogen production under visible light over NiO/ZnO hetero-system[J]. Appl Energy, 2011, 88(12): 4490-4495.

    9. [9] CHEN S F, ZHAO W, LIU W, ZHANG H, YU X L. Preparation, characterization and activity evaluation of p-n junction photocatalyst p-CaFe2O4/n-ZnO[J]. Chem Eng J, 2009, 155(1/2): 466-473.[9] CHEN S F, ZHAO W, LIU W, ZHANG H, YU X L. Preparation, characterization and activity evaluation of p-n junction photocatalyst p-CaFe2O4/n-ZnO[J]. Chem Eng J, 2009, 155(1/2): 466-473.

    10. [10] BAMWENDA G R, ARAKAWA H. The visible light induced photocatalytic activity of tungsten trioxide powders[J]. Appl Catal A: Gen, 2001, 210(1/2): 181-191.[10] BAMWENDA G R, ARAKAWA H. The visible light induced photocatalytic activity of tungsten trioxide powders[J]. Appl Catal A: Gen, 2001, 210(1/2): 181-191.

    11. [11] HU C C, NIAN J N, TENG H. Electrodeposited p-type Cu2O as photocatalyst for H2 evolution from water reduction in the presence of WO3[J]. Sol Energy Mat Sol C, 2008, 92(9): 1071-1076.[11] HU C C, NIAN J N, TENG H. Electrodeposited p-type Cu2O as photocatalyst for H2 evolution from water reduction in the presence of WO3[J]. Sol Energy Mat Sol C, 2008, 92(9): 1071-1076.

    12. [12] CHOU T P, ZHANG Q F, FRYXELL G E, CAO G Z. Hierarchically structured ZnO Film for dye-sensitized solar cells with enhanced energy conversion efficiency[J]. Adv Mater, 2007, 19(18): 2588-2592.[12] CHOU T P, ZHANG Q F, FRYXELL G E, CAO G Z. Hierarchically structured ZnO Film for dye-sensitized solar cells with enhanced energy conversion efficiency[J]. Adv Mater, 2007, 19(18): 2588-2592.

    13. [13] FU D Y, HAN G Y, MENG C F. Size-controlled synthesis and photocatalytic degradation properties of nano-sized ZnO nanorods[J]. Mater Lett, 2012, 72: 53-56.[13] FU D Y, HAN G Y, MENG C F. Size-controlled synthesis and photocatalytic degradation properties of nano-sized ZnO nanorods[J]. Mater Lett, 2012, 72: 53-56.

    14. [14] WANG S J, ZHANG X T, CHENG G, JIANG X H, LI Y C, HUANG Y B, DU Z L. Study on electronic transport properties of WO3/TiO2 nanocrystalline thin films by photoassisted conductive atomic force microscopy[J]. Chem Phys Lett, 2005, 405(1/3): 63-67.[14] WANG S J, ZHANG X T, CHENG G, JIANG X H, LI Y C, HUANG Y B, DU Z L. Study on electronic transport properties of WO3/TiO2 nanocrystalline thin films by photoassisted conductive atomic force microscopy[J]. Chem Phys Lett, 2005, 405(1/3): 63-67.

    15. [15] XIN G, GUO W, MA T L. Effect of annealing temperature on the photocatalytic activity of WO3 for O2 evolution[J]. Appl Surf Sci, 2009, 256(1): 165-169.[15] XIN G, GUO W, MA T L. Effect of annealing temperature on the photocatalytic activity of WO3 for O2 evolution[J]. Appl Surf Sci, 2009, 256(1): 165-169.

    16. [16] TIAN L H, YE L Q, LIU J Y, ZAN L. Solvothermal synthesis of CNTs-WO3 hybrid nanostructures with high photocatalytic activity under visible light[J]. Catal Commun, 2012, 17: 99-103.[16] TIAN L H, YE L Q, LIU J Y, ZAN L. Solvothermal synthesis of CNTs-WO3 hybrid nanostructures with high photocatalytic activity under visible light[J]. Catal Commun, 2012, 17: 99-103.

    17. [17] CHEN H Y, YANG W J, CHANG K P. Characterization of delafossite-CuCrO2 thin films prepared by post-annealing using an atmospheric pressure plasma torch[J]. Appl Surf Sci, 2012, 258(22): 8775-8779.[17] CHEN H Y, YANG W J, CHANG K P. Characterization of delafossite-CuCrO2 thin films prepared by post-annealing using an atmospheric pressure plasma torch[J]. Appl Surf Sci, 2012, 258(22): 8775-8779.

    18. [18] CHIU T W, YU B S, WANG Y R, CHEN K T, LIN Y T. Synthesis of nanosized CuCrO2 porous powders via a self-combustion glycine nitrate process[J]. J Alloy Compd, 2011, 509(6): 2933-2935.[18] CHIU T W, YU B S, WANG Y R, CHEN K T, LIN Y T. Synthesis of nanosized CuCrO2 porous powders via a self-combustion glycine nitrate process[J]. J Alloy Compd, 2011, 509(6): 2933-2935.

    19. [19] KETIR W, REKHILA G, TRARI M, AMRANE A. Preparation, characterization and application of CuCrO2/ZnO photocatalysts for the reduction of Cr(Ⅵ)[J]. J Environ Sci, 2012, 24(12): 2173-2179.[19] KETIR W, REKHILA G, TRARI M, AMRANE A. Preparation, characterization and application of CuCrO2/ZnO photocatalysts for the reduction of Cr(Ⅵ)[J]. J Environ Sci, 2012, 24(12): 2173-2179.

    20. [20] WANG J M, ZHENG P C, LI D, DENG Z H, DONG W W, TAO R H, FANG X D. Preparation of delafossite-type CuCrO2 films by sol-gel method[J]. J Alloy Compd, 2011, 509(18): 5715-5719.[20] WANG J M, ZHENG P C, LI D, DENG Z H, DONG W W, TAO R H, FANG X D. Preparation of delafossite-type CuCrO2 films by sol-gel method[J]. J Alloy Compd, 2011, 509(18): 5715-5719.

    21. [21] KIM S Y, LEE J H, KIM J J, HEO Y W. Preferential growth orientations of CuCrO2 films grown by pulsed laser deposition[J]. Curr Appl Phys, 2012, 12(4): S123-S126.[21] KIM S Y, LEE J H, KIM J J, HEO Y W. Preferential growth orientations of CuCrO2 films grown by pulsed laser deposition[J]. Curr Appl Phys, 2012, 12(4): S123-S126.

    22. [22] TONOOKA K, KIKUCHI N. Prepatation of traspatent CuCrO2: Mg/ZnO p-n junctions by pulsed laser deposition[J]. Thin Solid Films, 2006, 515(4): 2415-2418.[22] TONOOKA K, KIKUCHI N. Prepatation of traspatent CuCrO2: Mg/ZnO p-n junctions by pulsed laser deposition[J]. Thin Solid Films, 2006, 515(4): 2415-2418.

    23. [23] CHIU T W, YANG Y C, YEH A C, WANG Y P, FENG Y W. Antibacterial property of CuCrO2 thin films prepared by RF magnetron sputtering deposition[J]. Vacuum, 2013, 87: 174-177.[23] CHIU T W, YANG Y C, YEH A C, WANG Y P, FENG Y W. Antibacterial property of CuCrO2 thin films prepared by RF magnetron sputtering deposition[J]. Vacuum, 2013, 87: 174-177.

    24. [24] 王建祺, 吴文辉, 冯大明. 电子能谱学(XPS/XAES/UPS)引论[M]. 北京: 国防工业出版社, 1992, 519-558. (WANG Jian-qi, WU Wen-hui, FENG Da-ming. Electron spectroscopy (XPS/XAES/UPS) introduction[M].Beijing: National Defence Industry Press, 1992, 519-558.)[24] 王建祺, 吴文辉, 冯大明. 电子能谱学(XPS/XAES/UPS)引论[M]. 北京: 国防工业出版社, 1992, 519-558. (WANG Jian-qi, WU Wen-hui, FENG Da-ming. Electron spectroscopy (XPS/XAES/UPS) introduction[M].Beijing: National Defence Industry Press, 1992, 519-558.)

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  618
  • HTML全文浏览量:  32
文章相关
  • 收稿日期:  2013-06-06
  • 网络出版日期:  2013-08-25
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net