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固载化ZnCl2催化合成3-甲基-3-丁烯-1-醇

刘海超 ,  刘季铨 ,  郭启文 ,  李连地 ,  李洪广 ,  闻霞 ,  肖福魁 ,  赵宁 ,  魏伟 ,  孙予罕

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引用本文: 刘海超, 刘季铨, 郭启文, 李连地, 李洪广, 闻霞, 肖福魁, 赵宁, 魏伟, 孙予罕. 固载化ZnCl2催化合成3-甲基-3-丁烯-1-醇[J]. 燃料化学学报, 2013, 41(9): 1146-1152. shu
Citation:  LIU Hai-chao, LIU Ji-quan, GUO Qi-wen, LI Lian-di, LI Hong-guang, WEN Xia, XIAO Fu-kui, ZHAO Ning, WEI Wei, SUN Yu-han. Synthesis of 3-methy-3-buten-1-ol catalyzed by immobilized ZnCl2[J]. Journal of Fuel Chemistry and Technology, 2013, 41(9): 1146-1152. shu

固载化ZnCl2催化合成3-甲基-3-丁烯-1-醇

    通讯作者: 魏伟 (1971-), 研究员, Tel: 0351-4049612, E-mail: weiwei@sxicc.ac.cn。
摘要: 采用碾磨-活化法制备了SiO2-ZnCl2(Silzic)催化剂,并将其用于异丁烯与甲醛Prins缩合合成3-甲基-3-丁烯-1-醇(MBOH)。系统研究了温度、物料比、时间和催化剂的组成及用量对该反应的影响。结果表明,在不同的条件下,甲醛都保持着99%以上的高转化率;然而,不同的条件对MBOH的选择性和收率的影响程度不同,其中,反应温度、催化剂的酸量是影响该反应的关键因素;物料比和反应时间对MBOH的选择性和收率的影响相对较小。实验得到最佳的反应条件为,反应温度210 ℃、二氧六环8 g、三聚甲醛1.5 g、n(异丁烯)/n(三聚甲醛)=7:1、30 mg 1 mmol/g Silzic 和反应时间2 h,在此条件下MBOH的选择性和收率可分别达到93.8%和93.4%。当催化剂循环使用五次时,MBOH的收率降为85.2%,表明该催化剂具有一定的重复使用性。

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  • 收稿日期:  2012-11-12
  • 网络出版日期:  2013-03-15
通讯作者: 陈斌, bchen63@163.com
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