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Iodide analysis by ion chromatography on a new stationary phase of polystyrene-divinylbenzene agglomerated with polymerized-epichlorohydrin-dimethylamine

Mu-Hua Wang ,  Zhong-Ping Huang ,  Jun-Wei Liu ,  Jie He ,  Jia-Jie Zhang ,  Yan Zhu

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Citation:  Mu-Hua Wang, Zhong-Ping Huang, Jun-Wei Liu, Jie He, Jia-Jie Zhang, Yan Zhu. Iodide analysis by ion chromatography on a new stationary phase of polystyrene-divinylbenzene agglomerated with polymerized-epichlorohydrin-dimethylamine[J]. Chinese Chemical Letters, 2015, 26(8): 1026-1030. doi: 10.1016/j.cclet.2015.05.002 shu

Iodide analysis by ion chromatography on a new stationary phase of polystyrene-divinylbenzene agglomerated with polymerized-epichlorohydrin-dimethylamine

    • 通讯作者: Yan Zhu,
  • 基金项目:

    This research was financially supported by Natural Science Foundation of Zhejiang Province (Nos. Y4110532, LQ13B050001, LY12B05003) (Nos. Y4110532, LQ13B050001, LY12B05003)

    Universities in Zhejiang Province (No. FX2013148) (No. FX2013148)

    Equipment Development Special of China (No. 2012YQ09022903) (No. 2012YQ09022903)

摘要: A new stationary phase for iodide ion analysis has been developed. The cationic polymerepichlorohydrin-dimethylamine (PEPI-DMA) was served as modifier in synthesizing polyelectrolyte sorbents and the macroporous polystyrene-divinylbenzene (PS-DVB) resin was used as support. The positively charged polymer (PEPI-DMA) was electrostatically bonded to a negatively charged particle (PS-DVB sulfonated). The new stationary phase was characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR), elemental analysis, chemical adsorption and desorption measurements. The chromatographic evaluation of the new stationary phase was performed using various anions with a conductivity detector. The new stationary phase was also applied to the determination of iodide directly with a DC amperometric detector using a platinum working electrode and an Ag/AgCl reference electrode. The chromatographic conditions were optimized and the eluent solution contained 5 mmol/L HNO3 and 15 mmol/L NaNO3 at a flow rate of 1.0 mL/min and column temperature of 30 ℃. The applied voltage of the DC amperometric detector was 0.9 V. Under the optimum conditions, the linear range of the method was 0.2-50 mg/L for iodide ion with a correlation coefficient of 0.9990. The detection limit was 0.05 mg/L (calculated at S/N = 3) and the relative standard deviations (RSD, n = 6) were all less than 1% for retention time, peak area and peak height. This method was also utilized for the determination of iodide ions in samples of povidone iodine solution and kelp samples with satisfactory results.

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  • 发布日期:  2015-05-11
  • 收稿日期:  2014-12-29
  • 网络出版日期:  2015-04-14
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