Monitoring iodine adsorption onto zeolitic-imidazolate framework-8 film using a separated-electrode piezoelectric sensor

Da-Zhong Shen Ting-Ting Cai Xi-Lei Zhu Xiao-Long Ma Ling-Qiang Kong Qi Kang

Citation:  Da-Zhong Shen, Ting-Ting Cai, Xi-Lei Zhu, Xiao-Long Ma, Ling-Qiang Kong, Qi Kang. Monitoring iodine adsorption onto zeolitic-imidazolate framework-8 film using a separated-electrode piezoelectric sensor[J]. Chinese Chemical Letters, 2015, 26(8): 1022-1025. doi: 10.1016/j.cclet.2015.04.029 shu

Monitoring iodine adsorption onto zeolitic-imidazolate framework-8 film using a separated-electrode piezoelectric sensor

    通讯作者: Qi Kang,
  • 基金项目:

    The authors gratefully acknowledge financial support by National Natural Science Foundation of China (Nos. 21175084, 21275091) (Nos. 21175084, 21275091)

    Traditional Chinese Medicine Research (Hunan Normal University) (Hunan Normal University)

    Ministry of Education (No. KLCBTCMR2001-01)  (No. KLCBTCMR2001-01)

    Research Fund for the Doctoral Program of Higher Education of China (No. 20113704110003). (No. 20113704110003)

摘要: In this work, a separated-electrode piezoelectric sensor (SEPS), constructed by a naked quartz crystal mounted between two electrodes, is reported for applications in a corrosive gaseous phase. The response of SEPS was measured by an impedance analysis method. It was shown that SEPS has an excellent frequency stability because its quality factor is in the order of 105. The SEPS can be operated even with the electrode gap in air larger than 1 cm. Compared with a conventional quartz crystal microbalance, the resonant frequency of the SEPS is independent of the mass change in the electrode. The SEPS was applied to monitor the adsorption of iodine on quartz surface and zeolitic-imidazolate framework-8 (ZIF-8) film as well as in the transfer of iodine between two ZIF-8 films. The SEPS offers the advantages of easy preparation, corrosion-resistant and convenience in combination with mass and optical measurements.

English

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  • 发布日期:  2015-04-29
  • 收稿日期:  2015-01-05
  • 网络出版日期:  2015-04-03
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